• Journal of Radiation Research and Radiation Processing
  • Vol. 42, Issue 6, 060101 (2024)
Mingxing ZHANG, Junchang CHEN, and Shu'ao WANG*
Author Affiliations
  • State Key Laboratory of Radiation Medicine and Protection,School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions,Soochow University,Suzhou 215123,China
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    DOI: 10.11889/j.1000-3436.2024-0096 Cite this Article
    Mingxing ZHANG, Junchang CHEN, Shu'ao WANG. Research process of radiation-induced synthesis and functionalization of covalent organic frameworks[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(6): 060101 Copy Citation Text show less
    Common topological structures of two-dimensional COFs
    Fig. 1. Common topological structures of two-dimensional COFs
    Scheme for synthesis of COFs by electron beam radiation[12]
    Fig. 2. Scheme for synthesis of COFs by electron beam radiation[12]
    (a) Photo of the gamma-radiation unit,(b) the synthesis of γ-COF by gamma-radiation at different absorbed doses rate,(c) the synthesis of γ-COF by gamma-radiation under N2,Ar,and airatmosphere,(d) the synthesis of γ-COF by gamma-radiation in the vessel with different transparency,(e) the synthesis of γ-COF by gamma-radiation in a plastic tube,(f) comparison of the PXRD of the COFs synthesized by gamma rradiation method and conventional solvothermal method[17]
    Fig. 3. (a) Photo of the gamma-radiation unit,(b) the synthesis of γ-COF by gamma-radiation at different absorbed doses rate,(c) the synthesis of γ-COF by gamma-radiation under N2,Ar,and airatmosphere,(d) the synthesis of γ-COF by gamma-radiation in the vessel with different transparency,(e) the synthesis of γ-COF by gamma-radiation in a plastic tube,(f) comparison of the PXRD of the COFs synthesized by gamma rradiation method and conventional solvothermal method[17]
    Scheme for one-pot synthesis of COF-g-X%PAAc under γ ray radiation[51]
    Fig. 4. Scheme for one-pot synthesis of COF-g-X%PAAc under γ ray radiation[51]
    Scheme for synthesis of γ-COF/Cu-Xunder γ-ray radiation[52]
    Fig. 5. Scheme for synthesis of γ-COF/Cu-Xunder γ-ray radiation[52]
    (a) Static sorption of γ-COF and γ-COF@Mo-X toward MB,(b) dynamic column penetration sorption curves of γ-COF and γ-COF@Mo-3,Electrostatic potential distribution mapping of (c) γ-COF and (d) molybdic acid. Interactions between (e) γ-COF and MB,(f) molybdic acid and MB,(g) Static sorption of γ-COF@Mo-3 and γ-COF@Mo-3~0 kGy toward MB[54]
    Fig. 6. (a) Static sorption of γ-COF and γ-COF@Mo-X toward MB,(b) dynamic column penetration sorption curves of γ-COF and γ-COF@Mo-3,Electrostatic potential distribution mapping of (c) γ-COF and (d) molybdic acid. Interactions between (e) γ-COF and MB,(f) molybdic acid and MB,(g) Static sorption of γ-COF@Mo-3 and γ-COF@Mo-3~0 kGy toward MB[54]
    Scheme for synthesis of TbDa-COF and [C2vimBr]x%-TbDa-COF[28]
    Fig. 7. Scheme for synthesis of TbDa-COF and [C2vimBr]x%-TbDa-COF[28]
    Scheme for synthesis of 3DCOF,3DCOF-g-VBC,and 3DCOF-g-VBPPh3Cl,and their SEM images[29]
    Fig. 8. Scheme for synthesis of 3DCOF,3DCOF-g-VBC,and 3DCOF-g-VBPPh3Cl,and their SEM images[29]
    Scheme for synthesis of [15C5]n%-(TzDa-G-x%)[55]
    Fig. 9. Scheme for synthesis of [15C5]n%-(TzDa-G-x%)[55]
    Scheme for synthesis of BDATN,rBDATN and rBDATN-HCl[56]
    Fig. 10. Scheme for synthesis of BDATN,rBDATN and rBDATN-HCl[56]
    Mingxing ZHANG, Junchang CHEN, Shu'ao WANG. Research process of radiation-induced synthesis and functionalization of covalent organic frameworks[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(6): 060101
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