The ability to generate and manipulate broadband chiral terahertz waves is essential for applications in material imaging, terahertz sensing, and diagnosis. It can also open up new possibilities for nonlinear terahertz spectroscopy and coherent control of chiral molecules and magnetic materials. The existing methods, however, often suffer from low efficiency, narrow bandwidth, or poor flexibility. Here, we propose a novel type of laser-driven terahertz emitters, consisting of metasurface-patterned magnetic multilayer heterostructures, that can overcome the shortcomings of the conventional approaches. Such hybrid terahertz emitters combine the advantages of spintronic emitters for being ultrabroadband, efficient, and highly flexible, as well as those of metasurfaces for the powerful control capabilities over the polarization state of emitted terahertz waves on an ultracompact platform. Taking a stripe-patterned metasurface as an example, we demonstrate the efficient generation and manipulation of broadband chiral terahertz waves. The ellipticity can reach >0.75 over a broad terahertz bandwidth (1 to 5 THz), representing a high-quality and efficient source for few-cycle circularly polarized terahertz pulses with stable carrier waveforms. Flexible control of ellipticity and helicity is also demonstrated with our systematic experiments and numerical simulations. We show that the terahertz polarization state is dictated by the interplay between laser-induced spintronic-origin currents and the screening charges/currents in the metasurfaces, which exhibits tailored anisotropic properties due to the predesigned geometric confinement effects. Our work opens a new pathway to metasurface-tailored spintronic emitters for efficient vector-control of electromagnetic waves in the terahertz regime.

- Advanced Photonics
- Vol. 3, Issue 5, 056002 (2021)
Abstract
Video Introduction to the Article
1 Introduction
Coherent terahertz sources driven by femtosecond laser pulses can now routinely generate sub-picosecond few-cycle terahertz waves with exceptionally stable carrier waveforms, which can be used in numerous fundamental studies and practical applications.1,2 The ability to manipulate the three-dimensional (3D) electric-field vector of such broadband terahertz waveforms can substantially broaden the applications of the terahertz technologies and open up new possibilities for studies of coherent light–matter interactions,3
Metasurfaces, two-dimensional (2D) metamaterials composed by subwavelength planar micro-structures (e.g., “meta-atoms”) with tailored electromagnetic responses, have greatly enriched our capability of wave manipulation in the terahertz regime.24
This, in fact, can be realized by employing the novel spintronic terahertz emitters composed of magnetic multilayer heterostructures.36
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In this work, we propose a novel spintronic-metasurface terahertz emitter, consisting of metasurface-patterned ferromagnetic (FM) and nonmagnetic (NM) heterostructures. Taking the prototypical stripe-pattern metasurface as an example, we demonstrate the generation and manipulation of chiral terahertz waveforms in an efficient and highly flexible manner. The ellipticity can reach for a broad terahertz bandwidth (1 to 5 THz), and the generation efficiency is comparable to the nonlinear crystals commercially available. Furthermore, by simply varying the transient spintronic-origin currents with an orientated external magnetic field, the emitter functionality can be actively controlled, leading to continuous tuning of the terahertz polarization state and helicity. We show that the geometric confinement in metallic microstructures can generate anisotropic screening charges/currents in responses to the laser-induced spintronic-origin currents, which, in turn, strongly modifies the polarization characteristics of the terahertz waves emitted from the whole device in the desirable way. Our work opens a new pathway to active metasurface-tailored spintronic devices for efficient generation and control over the electric-field vectors in the terahertz regime.
2 Principles and Methods
Figure 1(a) shows the schematic of the experimental setup. In our experiments, the ultrashort laser pulses (duration , center wavelength 1030 nm, and repetition rate 100 kHz) generated by a compressed Yb:KGW laser amplifier are used to excite the active spintronic-metasurface device. The high-quality pulse compression is enabled by solitary beam propagation in periodic layered Kerr media.43 The excitation pulse energy is , and the beam radius on the metasurface emitter is (see Sec. S1 in the Supplementary Material for details on the experimental setup). The metasurface emitter is composed of stripe-patterned FM/NM heterostructures. The FM/NM heterostructure consists of NM Pt (thickness of 3 nm) capped with FM (1.4 nm) and supported by a thick or substrate. We note that other FM metals and alloys, such as Fe, Co, and Co-Fe-B alloys, can also be used in substitution for since similar terahertz signals can be generated from the heterostructures composed of these materials.36 The stripe patterns are then fabricated by the standard optical lithography and ion beam etching process (see Sec. S2 in the Supplementary Material). The metasurface structures with different stripe widths () and spacings (), as well as on different substrates (, ), are investigated [see Fig. 1(a)]. In the experiments, the stripe orientation is fixed along the axis, while the magnetization of the FM layer () is saturated by an oriented external magnetic field () with a field magnitude of 200 mT, and the field orientation can be continuously adjusted in the plane. The field angle is defined as the angle between and the stripe orientation ( axis), as shown in Fig. 1(a). The applied field is much stronger than the anisotropy field of the FM film, thus the FM magnetization is expected to always align parallel to (see Sec. S3 in the Supplementary Material). Under femtosecond laser illumination, the longitudinal spin current () arising in the FM layer is converted into a transverse charge current () via the inverse spin-Hall effect (ISHE) in the NM layer, given by , where is the spin-Hall angle of the NM layer.37 As a result, in our experiments, the laser-induced charge current always flows perpendicularly to and serves as an active driving source of the stripe-patterned metasurface [see Fig. 1(a)]. The emitted terahertz field and its polarization state are then detected by the polarization- and time-resolved terahertz spectroscopy setup based on electro-optic sampling (EOS)44
Figure 1.Generation of chiral terahertz waves from a stripe-patterned spintronic-metasurface emitter. (a) Schematic of the experimental setup. The femtosecond pulse is focused to excite a stripe-patterned spintronic-metasurface emitter along the
3 Results
We first present evidence showing that the metasurface can influence the device functionality by inducing strong amplitude and phase modulations onto the emitted terahertz waveforms. The EOS signals for the terahertz-wave components polarized parallel () and perpendicular () to the stripes are plotted in Fig. 2(a). Clearly, the perpendicular electric-field amplitude is strongly suppressed compared to , which is consistent with previous work.38,47 The results of the peak-to-peak amplitude [see Figs. 2(a) and 2(b)] as a function of are summarized in Fig. 2(c). The results of both and exhibit a sinusoidal behavior, while a angle shift can be observed. Furthermore, our results in Figs. 2(a) and 2(b) show that the terahertz waveforms, respectively, for the two orthogonal polarizations, possess almost identical temporal waveforms. This conclusion is further corroborated by the normalized spectra shown in Fig. 2(d), which displays identical spectral shapes for each polarization, although the spectrum of is blue-shifted compared to .38,47 The coherent detection of EOS allows us to retrieve the phase information, and, most interestingly, the phase difference () stays close to throughout the entire spectrum [see Fig. 2(e)]. This clearly indicates the generation of chiral terahertz waves. It is worthy to note that the above results are obtained from a device with , and the filling factor (FF) on a substrate. Similar observations can be made on other metasurface geometries (see Sec. S5–S7 in the Supplementary Material).
Figure 2.Modulation of terahertz spectrum and phase due to metasurface structure. (a) Terahertz waveforms of
Our findings here are distinct from past works, which only focused on the amplitude modulation and the spectral shift of the terahertz waves from the stripe-patterned terahertz emitters.38,47 Instead, our results clearly show that the directions parallel and perpendicular to the stripes define a set of canonical coordinates, in which the terahertz waveforms of and are decoupled from each other and possess a broadband quarter-wave phase difference. This is the key for the generation and manipulation of the chiral terahertz waves.
The above observations can be conceptually captured by a geometric-confinement model, which considers the dynamics and the interplay of the spintronic-origin current density (), as well as the transient metasurface-induced charges () and current density () that flows in the direction [see Figs. 1(b) and 1(c)]. According to Ohm’s law, the complex electric-field component () of the emitted terahertz wave is proportional to the complex magnitude of the total current density flowing in the same direction () by and ,36,37 where is the proportionality constant which is determined by the conductance of the metal layer and the metasurface geometry, and the minus sign for the perpendicular direction results from our measurement geometry [see Fig. 1(c)]. As shown in Fig. 1(c), along the stripes ( axis), the current density is solely contributed by the -component of , given by , where represents the complex magnitude of . On the other hand, in the direction perpendicular to the stripes ( axis), the current density consists of both the component of and the metasurface-induced “counteractive” current , which yields [see Fig. 1(c)]. The counteractive current is driven by the electric field built up by the transient charge density at the stripe boundaries with , where is the metal-layer conductivity, and is the constant of proportionality between the charge-induced electric field in the metal layer and the charge density (see Sec. S8 in the Supplementary Material). Here, can be considered as the result of the accretion of at the stripe boundaries. In the frequency domain, we derive that . For convenience of discussion, we further assume the low-frequency limit (), where and both become constant,48 and it finally yields and (see Sec. S8 in the Supplementary Material for the detailed derivation). Here, the low-frequency limit corresponds to the terahertz frequency, where the wavelength is much longer than the geometrical period () of the metasurface.
First of all, we obtain from the above model that the amplitude of is scaled by a factor of () when compared to , which leads to the observed suppression of [see Figs. 2(a) and 2(b)]. The factor of also explains the spectral blueshift of with respect to [see Fig. 2(d)]. Second, the amplitudes of and follow the sine- and cosine-functions of , respectively, which is consistent with Fig. 2(c). Finally, the complex amplitudes of and exhibit a spectral quarter-wave phase difference, which also agrees with the experimental results in Fig. 2(e). We note that, although this simple model can qualitatively explain the general features of our observations, the quantitative agreement over the entire spectrum is elusive. Neither is the inductive and capacitive coupling of the transient currents and charges between the stripes considered in this model. Hence, numerical simulations using the frequency-domain solver of COMSOL Multiphysics49 are further conducted to provide a comprehensive understanding of our results and to extract the microscopic mechanism (see Sec. S10 in the Supplementary Material).
The broadband quarter-wave phase difference naturally leads to chiral terahertz emission. In Fig. 3(a), we plot a typical time dependence of the electric-field vector for a chiral terahertz waveform obtained in our experiments, with the three projections displaying the waveforms of the mutually orthogonal components and , and their parametric plot. Here, a stripe pattern with and is excited by the laser pulses under . The generation of the chiral terahertz waveforms can be well captured by our numerical simulation performed for the same device and the same excitation conditions [see Fig. 3(a)]. As clearly shown in Fig. 3(b), the ellipticity and handedness of the emitted terahertz radiation can be conveniently and continuously controlled by changing the field angle . These results can also be well reproduced by the simulations (see Fig. S14 in the Supplementary Material).
Figure 3.Generation and manipulation of chiral terahertz waveforms. (a) Typical time dependence of the electric-field vector for a chiral terahertz waveform generated from a metasurface emitter with
To quantitatively characterize the polarization state of the emitted terahertz waveform, the broadband ellipticity is calculated by considering the spectral intensity and the phase difference over the entire spectrum,
In Fig. 3(c), we summarize the experimental results obtained from the devices with of the optimum , accompanied by the relative intensity of the terahertz fields. Here, is given as
In Fig. 3(d), we can also observe stepwise drops of beyond specific resonant frequencies (open symbols), which can be attributed to the collective coupling dynamics between the transient charges and currents over the entire metasurface [see Figs. 1(b) and 1(c)]. In Figs. 4(a) and 4(b), we plot the spectral amplitudes of and , respectively, normalized by . As shown in Fig. 4(a), the amplitude of increases linearly as a function of the terahertz frequency at low frequencies, which is consistent with our geometric-confinement model. Furthermore, multiple spectral anomalies can be observed, manifested as peaks and steps in the normalized spectra, as well as the sharp deviations of the relative phase from (see Fig. S7 in the Supplementary Material). Both the spectral and phase variations at the spectral anomalies are responsible for the plummets of field ellipticity, as labeled in Fig. 3(d). These anomaly features can be mostly well reproduced by the numerical simulations [see Figs. 4(c) and 4(d)], whereas the high-frequency dips present in the simulation for spectra [see Fig. 4(d)] are too weak to be observed experimentally.
Figure 4.Spectral anomaly due to coupling over the metasurface structure. (a) The normalized field spectra of
In Fig. 4(e), we summarize the anomaly frequencies (, denotes the low- and high-frequency anomalies) for different metasurface periods (). Here, we also include the results obtained from (colored symbols) and those from the emitters with an substrate (half-filled symbols) (see Sec. S6 and S7 in the Supplementary Material). Interestingly, is only related to the geometrical period of the metasurface, which can be characterized by a geometrical frequency , where is the speed of light in vacuum. This indicates that these anomalies originate from the collective dynamics across the entire metasurface. As shown in Fig. 4(e), we find that the low- and high-frequency anomalies can be well fitted by , where is the refractive index of the media. For the high-frequency anomalies (open symbols), the refractive index of the air () yields an excellent fit, while the low-frequency anomalies (filled symbols) can be fitted by the terahertz refractive indices of the substrates ( or 52), indicating that it originates from the dynamical coupling through the substrate layer. The different shapes of the anomaly features could be attributed to the Fano-like coupling between the narrow-band Rayleigh diffraction anomaly and the broad-band surface plasmon excitation, which is different for the TE and TM polarizations.53,54
With the help of the numerical simulations, we try to better understand the generation mechanism for chiral terahertz waves in the sub-wavelength scale. Taking and as an example, we plot in Figs. 4(f) and 4(g) the space- and frequency-distributions of the total current density in a single metal stripe, which is normalized by the amplitude of the driving current density . For [see Fig. 4(g)], the skin effect can be clearly observed, and the current density is largest near the stripe boundaries (). On the contrary, the current density of [see Fig. 4(f)] is almost completely suppressed at the boundaries due to the conductivity discontinuity, forming a standing-wave-like current distribution across the stripe. Indeed, the appearance of an additional node, which corresponds to a higher-order standing wave, starts to appear when the frequency is higher than ( in this case). In the low-frequency region, is almost completely subdued throughout the entire stripe, which is consistent with the geometric-confinement model. This can be understood by the fact that more transient charges () tend to be accumulated at the boundaries when the frequency is lower, leading to a stronger counteractive current (), which suppresses the flowing of . This observation confirms that the spatial confinement on the laser-induced transient currents in the stripe-patterned metasurface is responsible for the observed spectral and phase modulations, as well as for the generation of chiral terahertz waveforms. The spectral anomalies in Figs. 4(a)–4(d) can also be clearly resolved as the sharp peaks or steps of the current density in Figs. 4(f) and 4(g) at the corresponding frequencies.
4 Discussion
To increase the generation efficiency of the chiral terahertz waves, an intuitive way is to increase FF for a narrow by reducing . However, our results indicate that the ellipticity can be deteriorated due to the stronger dynamical coupling between the stripes and the appearance of the spectral anomalies. In Fig. 5(a), we show that for on a substrate decreases monotonically when . This can be explained by a stronger capacitive coupling between the stripes [see Fig. 1(c)], which results in weaker and, hence, less confinement of the transverse currents (see Sec. S8 in the Supplementary Material). This is supported by the simulation results of the geometrical factor , which rises monotonically when the stripes become denser [see Fig. 5(a)]. On the other hand, does not keep increasing for a lower FF as the stripes become more isolated. We find that this could be influenced by the appearance of the low-frequency anomalies () around the spectral peaks of the terahertz waves. Figure 5(c) shows the broadband ellipticity obtained from our simulation under different and FFs, the selected cuts of which generally agree with our experimental results [see Figs. 5(a) and 5(b)]. Notably, a high region exists in between FF=0.3-0.4 for a number of different . Given that the central frequency of the terahertz wave in our experiments is [Fig. 2(d)], and also the low-frequency anomaly is given by when the substrate is , the agreement of these two frequencies yields , which shows good correspondence with the left boundary for this high region [the white dashed line in Fig. 5(c)]. This result indicates that the coincidence of the value between the anomaly frequency and the terahertz central frequency could reduce . As a result, to optimize the field ellipticity under this situation, one should try to increase the anomaly frequencies beyond the spectral range of interest, which could be realized by choosing a substrate with a low terahertz refractive index in practice.
Figure 5.Optimizing the terahertz ellipticity of the stripe-patterned metasurface emitter. (a) The broadband ellipticity
The spintronic-metasurface emitter in our work represents a high-efficiency, flexible, and economical solution for generating broadband chiral terahertz radiations with high ellipticity and a tunable azimuthal angle. First of all, its generation efficiency is comparable to the standard terahertz emitters that are commercially available (see Sec. S4 in the Supplementary Material). Considering that a peak field strength up to can be generated from a homogeneous thin-film emitter when excited by a multi-millijoule laser amplifier,42 our approach has the potential to generate chiral terahertz fields up to under similar laser conditions [see Fig. 3(c)]. Second, the same emitting device can be compatible with different types of lasers, from a compact laser oscillator to a high-energy laser amplifier, highlighting the great flexibility of our method. This is also advantageous over the other chiral terahertz sources enabled by nonlinear frequency-conversion in gas plasmas10
5 Conclusion
Our work opens a new pathway to metasurface-tailored spintronic emitters for efficient generation and control of terahertz waves. The combination of ultrabroadband, efficient spintronic emitters and metasurfaces with predesigned functionality could lead to many more types of emitting devices for different spatial and temporal terahertz waveforms (e.g., vector beams, Airy beams, etc.) Although the laser-induced spintronic dynamics in the individual metasurface units are identical in this work, the sophisticated capability of modern spintronic nanoscale engineering has already allowed the manipulation of magnetization, magnetic anisotropy, and spin-current dynamics in each individual unit. This will offer a new degree of freedom to tailor the functionality of spintronic-metasurface devices, which could potentially lead to arbitrary vector-control of broadband terahertz waves in both space and time.
Chuanshan Tian is a professor in the Department of Physics and State Key Laboratory of Surface Physics at Fudan University. He leads a research group devoting to experimental study of exotic phenomena at surfaces and interfaces, with special interest in the development of advanced nonlinear optical spectroscopic techniques to resolve molecular and electronic structure at the interfaces that are relevant to renewable energy and environmental issues.
Lei Zhou is a “Xi-De” chair professor and chair of the Department of Physics at Fudan University. He works in the field of nanophotonics, was elected as an OSA Fellow in 2019, and won the second prize of National Natural Science of China in 2019. He is a funding co-editor-in-chief of Photonics Insights, a managing editor of Nanophotonics, and serves on the editorial board Physical Review Materials and EPJ Applied Metamaterials.
Yizheng Wu is a professor in the Department of Physics and State Key Laboratory of Surface Physics at Fudan University since 2005. His research interests span over several branches of magnetism and spintronics, including thin film magnetism, antiferromagnetic spintronics, spintronics THz emission and spin-dependent transport in single crystal system.
Zhensheng Tao is a professor in the Department of Physics and State Key Laboratory of Surface Physics at Fudan University since 2018. His research activity is devoted to experimental research in optics and condensed matter physics, with particular interest in ultrafast non-equilibrium light–matter interaction and the development of ultrafast technologies.
Biographies of the other authors are not available.
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