Author Affiliations
1State Key Laboratory of Advanced Fiber Materials, College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China2College of Materials Science and Engineering, Donghua University, Shanghai 201620, China3Renewable Energy Research Department, Niroo Research Institute, Tehran 1468613113, Iran4Department of Energy System Engineering, Faculty of Mechanical Engineering, K.N. Toosi University of Technology, Tehran 1991943344, Iran5Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, Chinashow less
【AIGC One Sentence Reading】:Inspired by natural elements, a fabric with CF-core/MnO2-shell is designed for efficient seawater evaporation. It offers superhydrophilicity, light-trapping, and suppressed electrolysis, achieving a high synergetic evaporation rate.
【AIGC Short Abstract】:Inspired by natural elements, researchers designed a fabric for efficient seawater desalination. Decorated with super-hydrophilic MnO₂ nanoplates on hydrophobic carbon fiber via electro-deposition, it achieves superhydrophilicity, light-trapping, and suppressed water electrolysis. This leads to high photo-thermal (2.3 kg m⁻² h⁻¹) and electrothermal (5.3 kg m⁻² h⁻¹) evaporation rates. Combined, it reaches a striking 8.5 kg m⁻² h⁻¹, offering a novel design for efficient seawater evaporation.
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Abstract
Photo/electro-thermal evaporation is a promising tactic for alleviating the scarcity of fresh water, but its practical application still faces many challenges such as weak photoabsorption, high vaporization enthalpy and serious water-electrolysis during photo-thermal/electrothermal evaporation. To solve these problems, inspired by black rose petal and electric heater, we report a biomimetic design of fabric for achieving efficient photothermal/electrothermal desalination. The photo/electrothermal fabric is fabricated by decorating super-hydrophilic MnO2 nanoplates as shell on hydrophobic carbon fiber (CF) as core via an electro-deposition method. MnO2 nanoplate decoration as a stone confers three fascinating features (birds): (I) the hydrophilic nature of MnO2 contributes to the fabric’s superhydrophilicity and decreased evaporation enthalpy (2032 kJ kg-1) in comparison with that (2410 kJ kg-1) of pure water; (II) nanoplate structure confers the light-trapping effect and thus the improved photoabsorption efficiency of 95.1%; (III) CF-core/MnO2-shell structure can effectively suppress electrolysis of water and lead to good electrothermal conversion property. As a result, CF/MnO2 fabric-based hanging evaporator shows the high photo-thermal evaporation rate of 2.3 kg m-2 h-1 at 1 sun (1 kW m-2) and electrothermal evaporation rate of 5.3 kg m-2 h-1 at 3 V. Importantly, by the combined effects of 1 sun and 3 V, CF/MnO2 fabric achieves a striking synergetic evaporation rate of 8.5 kg m-2 h-1, exceeding the sum (7.5 kg m-2 h-1) of the individual photo-thermal and electro-thermal evaporation rates. The present high synergetic evaporation performance benefits from efficient photo/electrothermal conversion of the fabric and sufficient water-supplementation at the fiber-water interface resulting from thermosiphon effect. Thus, this study offers a novel possibility in the rational design of photo-electrothermal materials for efficient evaporation of seawater.