
- Chinese Optics Letters
- Vol. 21, Issue 10, 103602 (2023)
Abstract
1. Introduction
At present, the magnetic Purcell effect[1] is receiving more attention in photonic applications, particularly in optical antennas[2] and metamaterials[3], which enables further employment and characterizing of magnetic emission in nanophotonic structures[4]. In common systems, the strength of the magnetic dipole transitions is usually weaker than the electric dipole transitions by several orders[5]. But some emitters, such as lanthanide ions[6] and quantum dots[7], have considerable magnetic dipole magnitudes[8] within the optical range, allowing them to act as magnetic quantum emitters (MQEs). To maximize the magnetic Purcell effects, it is crucial to use nanostructures that support strong magnetic resonances. Metallic split-ring resonators[9,10], dielectric nanospheres[11], dielectric nanodisks[12,13], dimer antennas[2,14], diabolo antennas[15,16], and nanohole (or nanoparticle) arrays[3,17] have been investigated for providing magnetic resonances with a high magnetic density of states (MLDOS).
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The nanostructures mentioned above are made of only dielectric or metal, each possessing intrinsic advantages and disadvantages. Dielectric nanostructures exhibit low intrinsic loss and high radiation directivity but offer weaker field enhancement, while metal ones have ultrastrong field confinement but suffer from substantial Ohmic loss. Nevertheless, hybrid nanostructures can achieve the balance between low loss (higher quality factors) and high confinement (smaller mode volumes). By controlling the size, shape, and composition of the hybrid structures, researchers can tailor the properties of the hybrid resonance to meet specific requirements, offering a promising avenue for the development of high-performance nanophotonic devices. Multilayer nanodisks[18], nanodisk-nanoparticle structures[19,20], dimer antennas[21], Yagi–Uda antennas[22], nanoparticle-cavity systems[23–26], metal-semiconductor nanowires[27,28], and hybrid gratings[29] have been discussed in previous work. These nanostructures have exhibited their potentials in nanolasers[30,31], strong light–matter interaction[24,26], radiation directivity control[32,33], nonlinear effects[20,34,35], and sensing[36]. But these hybrid structures are mostly employed in producing considerable electric Purcell enhancement[37]. The magnetic Purcell enhancement, though important, has been rarely studied. Their potential in enhancing the magnetic Purcell effect needs further investigation via combining the advantages of dielectric and metal materials.
In this work, we propose a hybrid structure, including a dielectric nanoring and a metal nanorod. The structure can efficiently enhance the emission from both magnetic and electric dipole transitions within the optical communication band. Strong magnetic and electric optical resonances are both supported in our hybrid structure. Compared to a single nanoring or nanorod, the hybrid structure yields the higher magnetic (
2. Model Setup
The resonances in our hybrid structure originate from the hybridization of a silicon nanoring and a silver nanorod. For the single nanoring or nanorod, the magnetic dipole (MD) resonance of the nanoring[12] and the electric quadrupole (EQ) of the nanorod[41] are both located at 1360 nm. These resonances enable very strong magnetic or electric resonances so that the emitter can yield very high Purcell enhancement around the nanoring or the nanorod. Under the mode hybridization, the hybrid resonances appear at 1305 and 1430 nm, which demonstrate high magnetic and electric density of states (MLDOS and ELDOS), respectively. Moreover, the Ohmic loss is suppressed. Thus, the greater magnetic and electric Purcell enhancements can be achieved along with a high radiation efficiency. Particularly, the magnetic Purcell factor approaches 60, and the radiation efficiency remains steady above 95%. The large MLDOS are distributed in the region around the nanoring. The emitter can thus be positioned in relaxed fabrication requirements. Moreover, a 40-fold Purcell enhancement can be achieved in the gap between the nanoring and the nanorod. By narrowing the gap, the electric emission enhancement can be higher.
The hybrid structure consists of a silicon nanoring and a silver nanorod on a silica substrate, as shown in Fig. 1(a). The two components are separated by a gap with
Figure 1.(a) Schematic of our hybrid structure consisting of a silicon nanoring, a silver nanorod, and a silica substrate. Structural parameters are ticked out in the illustration. (b) Field profile of the magnetic-like resonance excited by the MQE (ticked out by a blue dot). (c) Purcell factor (solid line) and the radiation efficiency (pink dashed line) under the excitation of the MQE. The Purcell factors of a single nanoring are illustrated by a blue dashed line. (d) Field profile of the electric-like resonance excited by the EQE (ticked out by a dark red arrow). (e) The Purcell factor (solid line) and the radiation efficiency (pink dashed line) under the excitation of the EQE. The Purcell enhancement of a single nanorod is illustrated by a green dashed line. Cyan arrows depict the electric field around the hybrid structure in (b),(d).
The electromagnetic simulation is conducted in the commercial COMSOL software using finite element analysis. The size of the simulation module is
3. Magnetic and Electric Purcell Enhancement in the Hybrid Structure
3.1. Resonances in the hybrid structure
Our hybrid metal-dielectric structure supports the hybrid magnetic-like and electric-like resonances stemming from the MD and the EQ resonances in a single silicon nanoring and silver nanorod. Here, we set the resonances of a single nanoring or nanorod at 1360 nm (structural parameters can be found in the model setup above. More details are shown in the Supplementary Material). For the silicon nanoring, the MD resonance dominates at 1360 nm. It can provide high Purcell enhancement when the MQEs locates in the center[12]. For the silver nanorod, only the electric resonances are supported. The rod length is chosen as 870 nm with the EQ resonance dominating. EQEs can yield strong Purcell enhancement in the setup[41]. Superior to the single nanoring and nanorod, our proposed structure enables hybrid resonances with a further increase of local density of states (LDOS) along with low Ohmic loss.
When the two components are put together, two hybrid resonances move apart from the original MD and EQ resonances. The first is the magnetic-like resonance at 1305 nm [Fig. 1(c)]. It is excited by the MQE at the center of the nanoring. The emitter is 55 nm above substrate, whose polarization is perpendicular to substrate. Figure 1(b) demonstrates that the nanoring exhibits a strong MD field pattern. Due to the near-field coupling in the gap, the EQ on the rod is suppressed since its field pattern is perpendicular to the gap and does not overlap with the MD on the nanoring. Thus, the rod is only excited with the field pattern of the ED. Figure 1(c) reveals a larger magnetic Purcell enhancement in the magnetic-like resonance, and the emission linewidth is also reduced compared to the single nanoring. This phenomenon can be interpreted as a result of the coupling between the nanorod and the nanoring. With a relatively weak excitation, the nanorod acts as a reflector rather than a resonator[43]. The hybrid system can be seen as a combination of two nanorings with MDs on them. The hybrid resonance based on two MD resonances can support narrower linewidth and higher magnetic Purcell enhancement[2]. For the electric-like resonance located in 1430 nm, its field profile indicates a pattern of the EQ in the nanorod, while the nanoring has a weaker excitation of the ED. Because of the high field confinement of the gap surface plasmons, the electric-like resonance can support the strong electric Purcell enhancement, which surpasses the emission enhancement with a single nanorod [Fig. 1(e)].
3.2. Magnetic and electric Purcell enhancements
We then investigate the magnetic or electric Purcell effects when the MQE or the EQE is situated at the different points of the hybrid nanostructure. For the magnetic Purcell effect, the MQE is located in the hollow region of dielectric nanoring, and its orientation is normal to the substrate. Such a setup can maximally excite the magnetic-like resonance[12,44] and surpasses the Purcell factor obtained in a single nanoring. Compared with the relevant work aimed at enhancing magnetic Purcell effects, the level of our hybrid structure is superior or comparable to dielectric nanospheres[11], metal diabolo antennas[16], and metal nanodisk arrays[45]. Additionally, the distance (55 nm) between the emitter and the structure is larger than the research above under similar Purcell enhancement, which brings convenience to nano-assembling. As shown in Fig. 1(c), the magnetic Purcell factor reaches a peak of 59 at 1305 nm [Fig. 1(c)] when the MQE is located at 55 nm above the substrate. Compared with the single nanoring, the Purcell enhancement has a higher peak along with a narrower linewidth in the hybrid structure. The higher and narrow-linewidth magnetic Purcell enhancement also originates from the mode coupling in the magnetic-like resonance, which can be seen as the coupling of two MDs on the nanoring. A similar situation was discussed in the metal-dielectric photonic structures[2,43]. At a particular gap width, the magnetic Purcell factor can be maximized, which will be discussed in Section 3.3. To characterize the radiation property of the hybrid structure, we adopt a radiation efficiency of
For the electric Purcell effect, the EQE is located in the middle of the gap. Its dipole orientation is normal to the nanorod, corresponding to the hotspot of the EQ resonance [Fig. 1(d)]. The two structures form a gap plasmon with a large ELDOS[46], resulting in greater Purcell enhancement compared with a single nanorod. As the gap decreases, the electric Purcell factor displays a dramatic rise, which will be discussed in the following section. The peak of the electric Purcell factor is 46 at 1430 nm. Importantly, the radiation efficiency keeps at a very high level above 95% [Fig. 1(e)], which is useful for far-field light manipulations. The suppression of Ohmic loss can be attributed to the ultra-confined resonance with the existence of low-loss dielectric materials[47]. In our hybrid structure, the MQE and the EQE excite highly-confined resonances with low absorption, resulting in both a strong magnetic and electric Purcell enhancements along with a high radiation efficiency. These advantages of the hybrid structure may advance efficient nanoscale photon sources with a simpler arrangement.
3.3. Influence of structural and material parameters on Purcell factors
In the following section, we discuss the influence for Purcell enhancement under the variations of structural and material parameters. Here, the gap width
When the gap width
Figure 2.Variations of the magnetic and electric Purcell enhancement under some structural parameters in the magnetic (electric)-like resonance. Magnetic and electric Purcell factors as a function of (a),(b) gap width g, (c),(d) substrate refractive index n, (e),(f) inner radius of the nanoring rin, and (g),(h) length of nanorod lrod.
The refractive index
The inner radius
The rod length
3.4. Insensitivity of the Purcell factors to the emitter’s position
In the following, we investigate the influence of the emitter’s position on the Purcell factors. Our findings reveal that the Purcell factor remains high within a range of several 100 nm in the near-field region. Interestingly, the deviation of the emitter from the center of the nanoring or the gap can bring even higher magnetic and electric Purcell enhancements. These results demonstrate the flexibility in our hybrid nanostructure and thus provide more convenience in nano-fabrications. The large magnetic Purcell enhancement can be achieved inside the nanoring and in the hollow region[50], while the electric Purcell enhancement keeps a high level when the EQE locates around the nanorod[41]. These hotspots of enhancement also correspond to the field hotspots in magnetic and electric-like resonances [Figs. 1(b) and 1(d)].
Considering the magnetic Purcell effect, the Purcell factors keep at a high level around the nanoring. Figure 3(a) displays the Purcell factors when the MQE moves through a path through the center of the nanoring and normal to the nanorod. The Purcell factor reaches maximums around 90 at inner boundaries. A similar situation also manifests in Fig. 3(b). The deviation from the center does no harm to but benefits the higher emission enhancement. Moreover, the Purcell factors remain steady at 60 when the MQE intrudes into the nanorod. Figure 3(c) reveals the transition of the Purcell factor when the distance to the substrate of the MQE changes. The MQE can be placed at 50 nm above the substrate where the Purcell factor reaches the maximum of 60. When the MQE is closer to the substrate or comes into the substrate, the Purcell factor exhibits a decrease.
Figure 3.Variation of the magnetic and electric Purcell enhancement when the emitter’s position moves. (a)–(c) Magnetic Purcell factors when the MQE moves along the three paths depicted in the insets. The MQE feels the strongest emission enhancement at the inner boundaries. (d)–(f) The electric Purcell factors when the EQE moves along 3 paths depicted in the insets. The peak enhancement appears at the boundary of the nanorod. (g) Illustration of some specific points. The origin is set at the center of the nanoring and on the substrate. Some specific positions are also ticked out by Roman numerals I–V.
The electric Purcell enhancement is also insensitive to the position of the EQE and remains high when the EQE lies around the nanorod. In Fig. 3(d), there is nearly no ELDOS enhancement when the EQE is close to the nanoring. On the contrary, the Purcell factor of the EQE increases in the vicinity of the nanorod[51]. We find that the electric Purcell factor approaches 70 at the nanorod boundaries. In Fig. 3(e), the EQE yields the highest Purcell factor of 45 at the gap center. For both the large Purcell enhancement and experimental practicability, the EQE is suitable to locate in the gap. Note that in real experiments, it cannot be positioned too close to the nanorod boundary because it may induce quantum effects[52,53], which is not included in the electromagnetic simulation. Figure 3(f) reveals the influence of the distance from the substrate. The trend of the Purcell enhancement is similar to that of the MQE. The largest enhancement appears at 40 nm above the substrate, and when the EQE moves down into substrate or away from structure, the Purcell factor will drop.
4. Magnetic and Electric Purcell Enhancement and Far-Field Radiation in an Array
In this section, we explore the emission properties in an array composed of the hybrid structures [Fig. 4(a)]. The emission of a single MQE or EQE can be modulated under the hybrid resonance joined by the array cells. For the emission enhancement, the magnetic Purcell factor is even larger than that in the individual structure. The far-field radiation from the MQE also exhibits a high directivity. Every cell in the array is an individual hybrid metal-dielectric structure with the same setup as above. The intervals between rows and columns are
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Figure 4.Purcell enhancement, radiation efficiency, and far-field radiation in a 9 × 9 array of hybrid structures. (a),(d) Field profiles of the array excited by the MQE (or EQE) situated at the central cell. (b),(e) Radiation properties including the magnetic (electric) Purcell factors and the radiation efficiency. The right insets give schematics of the 9 × 9 array excited by the MQE or the EQE. (c),(f) The far-field radiation of the array (or the individual structure) excited by the MQE or the EQE. Compared with the individual structure, the far-field radiation exhibits a more directional pattern.
When the array is excited by the MQE, the advantages manifest in the larger magnetic Purcell enhancement and effective far-field radiation. The maximum Purcell enhancement is close to 100 folds at 1330 nm, higher than that of the individual structure mentioned above. The greater Purcell enhancement can be attributed to the existence of more adjacent structures[54]. For the far-field radiation, the radiation efficiency maintains above 90%. The modulation of the array can be described by an array factor[55], making the far-field radiation exhibit several main lobes and many side lobes. Under the excitation of the MQE, the excitation of each cell is close to the magnetic-like resonance, and the array factor has an approximate form of,
When the EQE excites the array, the maximum Purcell factor remains at the same level, as compared with an individual structure, and reaches 45 around 1400 nm. In the case of the excitation of EQE, the resonance of each cell is more complicated. In the central cell, the electric-like resonance is excited. In the adjacent and remoter cells, the excitation is relatively weak and more similar with magnetic-like resonance [Fig. 4(d)]. Figure 4(f) depicts the far-field radiation. The enhancement of the array factor is relatively low in the normal direction, making the side lobes obvious[56]. Moreover, the metal absorption is still suppressed. The radiation efficiency also stays above 89%.
5. Conclusion
Here, we propose a hybrid metal-dielectric structure composed of a silicon nanoring and a metal nanorod. The structure supports both large MLDOS and ELDOS, allowing for both a 60-fold magnetic Purcell enhancement and a 45-fold electric Purcell enhancement with a 70-nm gap. Its advantages show in the stronger field confinement and relatively low Ohmic loss when compared to using a single dielectric nanoring or metal nanorod. Moreover, the array that is composed of hybrid structures can modify the emission properties in directional far-field radiation and larger Purcell enhancement.
The structure can be fabricated by current nanofabrication techniques, such as electron beam lithography[22,57]. The emitter can be prepared by doping nanocrystals and then be assembled into the structure using atom force microscopy tips[4]. The hybrid structure also brings conveniences to nanofabrication. The limitation of positioning the emitters can be relaxed because of the high MLDOS and ELDOS in a wide region around the structure. The arrangement is relatively simple and also provides rich parameters to modulate resonances for optical antennas and metasurfaces. The proposed structure provides a wealth of parameters to modulate resonances for optical antennas and light-emitting metasurfaces. By combining the MD and the ED, the EQ resonances in both the dielectric and metal structures, and it can be easily optimized for specifical designs. The magnetic and electric Purcell enhancement also provides a route to selective excitation for photon sources on integrated circuits. Its applications are diverse, from increasing emission rate of lanthanide ions to enhancing and monitoring photochemical reactions such as photocatalysis.
References
[46] J. T. Hugall, A. Singh, N. F. Van Hulst. Plasmonic cavity coupling. ACS Photonics, 5, 43(2018).
[55] C. A. Balanis. Antenna Theory: Analysis and Design(2005).

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