• Laser & Optoelectronics Progress
  • Vol. 61, Issue 9, 0900003 (2024)
Yingli Liu, Taotao Mu*, and Shaohua Chen
Author Affiliations
  • School of Instrument Science and Opto-Electronics Engineering, Beijing Information Science & Technology University, Beijing 100192, China
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    DOI: 10.3788/LOP231206 Cite this Article Set citation alerts
    Yingli Liu, Taotao Mu, Shaohua Chen. Research Progress of Shifted Excitation Raman Difference Spectroscopy[J]. Laser & Optoelectronics Progress, 2024, 61(9): 0900003 Copy Citation Text show less
    Overview of acetonitrile differential Raman spectroscopy processing steps. (a) Raw spectra at two different excitation wavelengths; (b) differential spectrum; (c) Raman spectrum restored using integral method; (d) ideally, Raman spectrum restored using integral method
    Fig. 1. Overview of acetonitrile differential Raman spectroscopy processing steps. (a) Raw spectra at two different excitation wavelengths; (b) differential spectrum; (c) Raman spectrum restored using integral method; (d) ideally, Raman spectrum restored using integral method
    Raman spectra reduced by curve fitting method
    Fig. 2. Raman spectra reduced by curve fitting method
    Acetonitrile differential Raman spectra. (a) Raman spectra of acetonitrile excited by 784.5 nm and 785.5 nm wavelengths; (b) deconvolution and restore of Raman spectra
    Fig. 3. Acetonitrile differential Raman spectra. (a) Raman spectra of acetonitrile excited by 784.5 nm and 785.5 nm wavelengths; (b) deconvolution and restore of Raman spectra
    Workflow of NNLS based spectral reconstruction[15]
    Fig. 4. Workflow of NNLS based spectral reconstruction[15]
    Optical path structure of SERDS instrument. (a) Structure diagram of SERDS with dual-wavelength lasers at 532 nm and 526 nm[37]; (b) structure diagram of SERDS based on external cavity tunable semiconductor laser[38]; (c) optical path of SERDS based on dual-wavelength laser and area array CCD[44]; (d) internal structure diagram of portable SERDS[41]
    Fig. 5. Optical path structure of SERDS instrument. (a) Structure diagram of SERDS with dual-wavelength lasers at 532 nm and 526 nm[37]; (b) structure diagram of SERDS based on external cavity tunable semiconductor laser[38]; (c) optical path of SERDS based on dual-wavelength laser and area array CCD[44]; (d) internal structure diagram of portable SERDS[41]
    Instrument structure diagram of multi-wavelength defluorescence Raman spectrometer[46]
    Fig. 6. Instrument structure diagram of multi-wavelength defluorescence Raman spectrometer[46]
    Raw spectra, difference spectra, and reconstructed spectra of tree pollen and non-tree pollen under excitation at 784‒786 nm wavelength[52]
    Fig. 7. Raw spectra, difference spectra, and reconstructed spectra of tree pollen and non-tree pollen under excitation at 784‒786 nm wavelength[52]
    Raman spectra of nasopharyngeal tissue in vitro excited at the wavelength of 784.5 nm and 785.2 nm with different detection distances[54]. (a) 5 mm; (b) 10 mm; (c) 15 mm; (d) normalized shifted excitation Raman difference spectroscopy with different detection distances
    Fig. 8. Raman spectra of nasopharyngeal tissue in vitro excited at the wavelength of 784.5 nm and 785.2 nm with different detection distances[54]. (a) 5 mm; (b) 10 mm; (c) 15 mm; (d) normalized shifted excitation Raman difference spectroscopy with different detection distances
    MaterialRaman bands /cm-1Analysis methodReference
    Food wrapping paper

    360,430,464,674,790,1048,1096

    153,280,711,1085

    150,277,461,619,988,1085,1138

    222,288,406,606

    PCA,FDA20
    Medicine plastic packaging bottle

    632,810,973,1096,1147

    842,1289,858

    PCA,FDA,ANN-MLP/RBF21
    Plastic bottle cap

    393

    807,1073,1144

    841,1326

    PCA,FDA,HCM22
    Plastic medicine bottle

    810,842,973,1147,1167,1330,1459

    1063,1129,1295,1440,2721,2848

    280,711,1085

    PCA,HCM,FDA,ANN23
    Dairy packaging

    628,852,1096,1284,1617,1731

    1058,1124,1284,1441

    804,836,969,1152,1328,1458

    616,788,997,1027,1188,1604

    1083

    1090,1120,1295,1377,1441

    Cluster analysis25
    Pharmaceutical plastic and aluminum packaging sheet

    1059,1125,1289,1429

    1157,1330,1458

    625,684

    1000,1029

    1283,1602,1716

    PCA,between-group linkage,system clustering26
    Disposable plastic lids

    900,810,1322,842,809,841

    1170,1129,1063,999

    1602,1449,1327,220,1031

    K-means27
    Edible oil barrel

    1433,1288,1121,1053

    1720,1608,1087,849,624

    K-means28
    Food plastic packaging box

    632,858,1096,1289,1614,1727

    810,842,973,1147,1167,1330

    1063,1129,1295,1440,2721,2848

    Cluster analysis29
    Clear plastic tape

    810,842,973,1147,1167,

    1330,1459

    PCA,system clustering,K-means30
    Car lampshade

    596,808,986,1184,1450,1734

    618,790,997,1027,1154,1193,

    1447

    632,702,822,884,1108,1230

    PCA,SOM,multiple unordered logistic regression,SVM31
    Eye drops plastic bottle1059,1125,1292,1437,2006K-means32
    Rubber gloves

    291,366,491,819,1002,1039,

    1244,1375,1665

    250,467,759,916,1011,1063,

    1217,1306,1641

    243,519,856,925,988,1231,

    1302,1442,1643

    218,736,1002,1276,1303,

    1437,1668

    Cluster analysis33
    Wire plastic sheath

    361,625,684,912,1080,

    1153,1172,1259,1329,1429

    PCA,K-means,cluster analysis35
    Plastic toothbrush handle

    810,842,973,1147,1167,1330

    632,858,1096,1289,1614,1727

    Characteristic peak peak position grouping36
    Table 1. Summary of the main Raman bands used in item classification analysis