In order to monitor industrial chimney emissions accurately and effectively, based on the optical properties of SO₂ and carbon black particles, a dual-channel ultraviolet imaging remote sensing monitoring system was developed. The center wavelength of the two spectral channels were set at 310 nm and 330 nm, respectively. The SO₂ concentration image was obtained by the optical thickness difference of the two channels, and the particles concentration image was obtained by the 330 nm channel. With the plume speed obtained from the density image by the Optical-flow method, the emission rates of SO₂ and carbon black particle were calculated from them. The results show that the emission rates of SO₂ and carbon black particles from the industrial chimney are 72.48±3.16 kg/h and 6.33±1.18 kg/h, respectively. In this experiment, the SO₂ and carbon black particles emitted from industrial chimney were monitored by ultraviolet cameras simultaneously. A high time and spatial resolution was provided with dual-channel ultraviolet imaging remote sensing monitoring in this experiment, and the measurement results are accurate and intuitive. This method has obvious technical advantages and great application prospects in remote sensing of industrial exhaust, ship exhaust and volcanic eruption pollutions.