• Journal of Inorganic Materials
  • Vol. 38, Issue 12, 1387 (2023)
Tingting MA1,2, Zhipeng WANG1,2, Mei ZHANG1,2, and Min GUO1,2,*
Author Affiliations
  • 11. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China
  • 22. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
  • show less
    DOI: 10.15541/jim20230098 Cite this Article
    Tingting MA, Zhipeng WANG, Mei ZHANG, Min GUO. Performance Optimization of Ultra-long Stable Mixed Cation Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2023, 38(12): 1387 Copy Citation Text show less
    Flow chart for the preparation of perovskite films and device manufacturing by two-step spin coating in the air
    1. Flow chart for the preparation of perovskite films and device manufacturing by two-step spin coating in the air
    Crystal structures and morphologies of different samples
    2. Crystal structures and morphologies of different samples
    Photovoltaic performances of PSCs
    3. Photovoltaic performances of PSCs
    Photoelectric properties and energy levels of three perovskite films
    4. Photoelectric properties and energy levels of three perovskite films
    Interface transmission and carrier recombination characteristics of PSCs
    5. Interface transmission and carrier recombination characteristics of PSCs
    Long-term stabilities of three perovskite solar cells at (20±5) ℃, relative humidity <5% in the dark
    6. Long-term stabilities of three perovskite solar cells at (20±5) ℃, relative humidity <5% in the dark
    Dark state EIS profiles of (a) MP, (b) MFP, (c) CMFP PSCs before and after aging at (20±5) ℃ and relative humidity<5%
    7. Dark state EIS profiles of (a) MP, (b) MFP, (c) CMFP PSCs before and after aging at (20±5) ℃ and relative humidity<5%
    Thermal stability of three PSCs at (85±5) ℃ and relative humidity 20%-30% in the dark
    8. Thermal stability of three PSCs at (85±5) ℃ and relative humidity 20%-30% in the dark
    Wet stability of three PSCs at (20±5) ℃ and relative humidity 80%-90% in the dark
    9. Wet stability of three PSCs at (20±5) ℃ and relative humidity 80%-90% in the dark
    UPS profiles of three perovskite films
    S1. UPS profiles of three perovskite films
    XRD patterns of three perovskite thin films over time at 85 ℃, 20%-30% RH
    S2. XRD patterns of three perovskite thin films over time at 85 ℃, 20%-30% RH
    XRD patterns of three perovskite thin films over time at (20±5) ℃, 80%-90% RH
    S3. XRD patterns of three perovskite thin films over time at (20±5) ℃, 80%-90% RH
    SampleJsc /(mA•cm-2) Voc/V FFPCEmax/% Intergrated current density/(mA•cm-2)
    MP22.870.970.7416.3421.87
    MFP23.481.050.7618.6622.71
    CMFP23.301.060.7819.3422.37
    Table 1. Performance parameters of three best performing PSCs (Fig. 3 (e) and Fig. S1)
    SampleJsc /(mA•cm-2) Voc/V FFPCE/%PCEmax/%
    MP21.32±0.990.95±0.030.74±0.0215.11±0.8616.31
    MFP22.94±0.980.99±0.040.76±0.0317.18±0.6118.87
    CMFP22.24±0.771.03±0.030.78±0.0217.83±0.3319.34
    Table 1. Photovoltaic parameters of three types of perovskite solar cells
    Sampleτ1/ns τ2/ns B1B2τmean/ns
    MP33.6496.210.450.5568.05
    MFP31.7081.410.680.3247.61
    CMFP26.5177.120.220.7865.99
    Table 2. Fitting results of transient spectra (Fig. 4(d)) excited from the perovskite side
    SampleФ/eV $E_{\text{VB}}^{\text{F}}$/eV EVB/eV Eg/eV ECB/eV
    MP3.741.59-5.331.61-3.72
    MFP4.021.49-5.511.55-3.96
    CMFP3.931.47-5.401.55-3.85
    Table 3. EVB and ECB of three perovskite films calculated from UPS profiles (Fig. S1)
    Sample${{\tau }_{1}}^{\prime }$/ns ${{\tau }_{2}}^{\prime }$/ns ${{B}_{1}}^{\prime }$${{B}_{2}}^{\prime }$
    MP75.22422.180.470.53
    MFP35.421.420.380.62
    CMFP8.2134.520.760.24
    Table 4. Fitting results of transient spectra (Fig. 5(b)) excited from the FTO side
    Long-term stabilityRs/(Ω·cm2) Rrec/(Ω·cm2) Rnrec
    Before testingMP32.404932
    MFP27.187261
    CMFP21.8410890
    After testingMP47.9914620.30
    MFP39.8854300.75
    CMFP34.1691730.84
    Table 5. Fitting results of EIS (Fig. 7) data
    SampleFFnVnocJnscPCEn
    MP0.540.850.630.30
    MFP0.900.940.920.81
    CMFP0.880.960.900.85
    Table 6. Relative J-V values of three PSCs after long-term stability testing
    SampleFFnVnocJnscPCEn
    MP0.810.890.870.70
    MFP0.940.940.920.93
    CMFP0.950.960.950.99
    Table 7. Relative J-V values of three PSCs after thermal stability testing
    SampleFFnVnocJnscPCEn
    MP0.720.860.880.56
    MFP0.890.920.900.78
    CMFP0.910.960.920.84
    Table 8. Relative J-V values of three PSCs after wet stability testing
    Tingting MA, Zhipeng WANG, Mei ZHANG, Min GUO. Performance Optimization of Ultra-long Stable Mixed Cation Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2023, 38(12): 1387
    Download Citation