• Optical Instruments
  • Vol. 46, Issue 4, 56 (2024)
Mingtong CHEN, Canyu LIU, and Guanjun YOU*
Author Affiliations
  • School of Optical-Electrical and Computer Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
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    DOI: 10.3969/j.issn.1005-5630.202304040084 Cite this Article
    Mingtong CHEN, Canyu LIU, Guanjun YOU. Fluoride ions in situ passivation for thermally stable CsPbBr3 nanocrystals[J]. Optical Instruments, 2024, 46(4): 56 Copy Citation Text show less
    Morphology and XRD patterns of CsPbBr3 PNCs
    Fig. 1. Morphology and XRD patterns of CsPbBr3 PNCs
    Absorption and PL spectra of pristine and fluoride-treated CsPbBr3 NCs
    Fig. 2. Absorption and PL spectra of pristine and fluoride-treated CsPbBr3 NCs
    Suppression of emission thermal quenching
    Fig. 3. Suppression of emission thermal quenching
    Comparison of CsPbBr3 solution of pristine(①)and fluoride-doped(②)under natural and UV light after 7 days
    Fig. 4. Comparison of CsPbBr3 solution of pristine(①)and fluoride-doped(②)under natural and UV light after 7 days
    The TRPL spectra of CsPbBr3 of pristine and with different DDA moiety, the solid line is fitting curve.
    Fig. 5. The TRPL spectra of CsPbBr3 of pristine and with different DDA moiety, the solid line is fitting curve.
    样品类型F/%Br/%
    参照CsPbBr3034.07
    氟离子钝化CsPbBr315.0036.41
    Table 1. EDS of F and Br for CsPbBr3 PNCs
    参数未处理CsPbBr3CsPbBr3-DDABCsPbBr3-DDAF
    A1,τ1/ns(0.38,0.49)(0.18,1.50)(0.11,1.80)
    A2,τ2/ns(0.30,6.64)(0.66,7.31)(0.66,9.43)
    A3, τ3/ns(0.21,38.06)(0.15,21.81)(0.22,27.43)
    τavg/ns31.3012.7917.99
    τamp/ns10.358.3912.38
    Table 2. Calculations of triexponential fitting parameters