[1] Colombo P, Mera G, Riedel R and Sorar Polymer-derived ceramics: 40 years of research and innovation in advanced ceramics J. Am. Ceram. Soc. 93 1805–37

[2] Barrios E and Zhai L 2020 A review of the evolution of the nanostructure of SiCN and SiOC polymer derived ceramics and the impact on mechanical properties Mol. Syst. Des. Eng. 5 1606–41

[3] Greil P 2000 Polymer derived engineering ceramics Adv. Eng. Mater. 2 339–48

[4] Wang K S, Unger J, Torrey J D, Flinn B D and Bordia R K 2014 Corrosion resistant polymer derived ceramic composite environmental barrier coatings J. Eur. Ceram. Soc. 34 3597–606

[5] Riffard F, Joannet E, Buscail H, Rolland R and Perrier S 2017 Beneficial effect of a pre-ceramic polymer coating on the protection at 900 .C of a commercial AISI 304 stainless steel Oxid. Met. 88 211–20

[6] Hasemann G, Baumann T, Dieck S, Rannabauer S and Krüger M 2015 Polymer-derived ceramics as innovative oxidation barrier coatings for Mo–Si–B alloys Metall. Mater. Trans. A 46 1455–60

[7] Torrey J D and Bordia R K 2007 Phase and microstructural evolution in polymer-derived composite systems and coatings J. Mater. Res. 22 1959–66

[8] Torrey J D and Bordia R K 2008 Processing of polymer-derived ceramic composite coatings on steel J. Am. Ceram. Soc. 91 41–45

[9] Kraus T, Günthner M, Krenkel W and Motz G 2009 cBN particle filled SiCN precursor coatings Adv. Appl. Ceram. 108 476–82

[10] Liu M-Y, Wang H and Wang Y 2007 Enhancing flow boiling and antifouling with nanometer titanium dioxide coating surfaces AIChE J. 53 1075–85

[11] Szymanski W, Lipa S, Fortuniak W, Chojnowski J, Pospiech P, Mizerska U, Slomkowski S, Nyczyk-Malinowska A and Hasik M 2019 Silicon oxycarbide (SiOC) ceramic microspheres—structure and mechanical properties by nanoindentation studies Ceram. Int. 45 11946–54 Ceram. Soc. 80 2333–40

[12] Torrey J D and Bordia R K 2008 Mechanical properties of polymer-derived ceramic composite coatings on steel J. Eur. Ceram. Soc. 28 253–7

[13] Walter S, Soraru G D, Bréquel H and Enzo S 2002 Microstructural and mechanical characterization of sol gel-derived Si–O–C glasses J. Eur. Ceram. Soc. 22 2389–400

[14] Renlund G M, Prochazka S and Doremus R H 1991 Silicon oxycarbide glasses: part II. structure and properties J. Mater. Res. 6 2723–34

[15] Moysan C, Riedel R, Harshe R, Rouxel T and Augereau F 2007 Mechanical characterization of a polysiloxane-derived SiOC glass J. Eur. Ceram. Soc. 27 397–403

[16] Sorar`u G D, Kundanati L, Santhosh B and Pugno N 2019 Influence of free carbon on the Young’s modulus and hardness of polymer-derived silicon oxycarbide glasses J. Am. Ceram. Soc. 102 907–13

[17] Sorar`u G D, Dallapiccola E and D’Andrea G 1996 Mechanical characterization of sol–gel-derived silicon oxycarbide glasses J. Am. Ceram. Soc. 79 2074–80

[18] Janakiraman N and Aldinger F 2009 Fabrication and characterization of fully dense Si–C–N ceramics from a poly(ureamethylvinyl)silazane precursor J. Eur. Ceram. Soc. 29 163–73

[19] Goerke O, Feike E, Heine T, Trampert A and Schubert H 2004 Ceramic coatings processed by spraying of siloxane precursors (polymer-spraying) J. Eur. Ceram. Soc. 24 2141–7

[20] Colombo P, Paulson T E and Pantano C G 1997 Synthesis of silicon carbide thin films with polycarbosilane (PCS) J. Am. GD2010 `u

[21] Barroso G, Li Q, Bordia R K and Motz G 2019 Polymeric and ceramic silicon-based coatings—a review J. Mater. Chem. A 7 1936–63

[22] O’Shaughnessy W S, Gao M L and Gleason K K 2006 Initiated chemical vapor deposition of trivinyltrimethylcyclotrisiloxane for biomaterial coatings Langmuir 22 7021–6

[23] Zhao J J, Wang M H, Jebutu M S, Zhu M H and Gleason K K 2019 Fundamental nanoscale surface strategies for robustly controlling heterogeneous nucleation of calcium carbonate J. Mater. Chem. A 7 17242–7

[24] Sojoudi H, McKinley G H and Gleason K K 2015 Linker-free grafting of fluorinated polymeric cross-linked network bilayers for durable reduction of ice adhesion Mater. Horiz. 2 91–99

[25] O’Shaughnessy W S, Murthy S K, Edell D J and Gleason K K 2007 Stable biopassive insulation synthesized by initiated chemical vapor deposition of poly(1,3,5-trivinyltrimethylcyclotrisiloxane) Biomacromolecules 8 2564–70

[26] Moon H et al 2015 Synthesis of ultrathin polymer insulating layers by initiated chemical vapour deposition for low-power soft electronics Nat. Mater. 14 628–35

[27] Moreno-Couranjou M, Loyer F, Grysan P, Boscher N D and Choquet P 2020 Insights into switchable thermoresponsive copolymer layers by atmospheric pressure plasma-initiated chemical vapour deposition Plasma Process. Polym. 17 1900172

[28] Oh M S, Jeon M, Jeong K, Ryu J and Im S G 2021 Synthesis of a stretchable but superhydrophobic polymer thin film with conformal coverage and optical transparency Chem. Mater. 33 1314–20

[29] Trujillo N J, Wu Q G and Gleason K K 2010 Ultralow dielectric constant tetravinyltetramethylcyclotetrasiloxane films deposited by initiated chemical vapor deposition (iCVD) Adv. Funct. Mater. 20 607–16

[30] Nguyen B, Dabir S, Tsotsis T and Gupta M 2019 Fabrication of hydrogen-selective silica membranes via pyrolysis of vapor deposited polymer films Ind. Eng. Chem. Res. 58 15190–8

[31] Malen J A, Baheti K, Tong T, Zhao Y, Hudgings J A and Majumdar A 2011 Optical measurement of thermal conductivity using fiber aligned frequency domain thermoreflectance J. Heat Transfer 133 081601

[32] Ong W-L, O’Brien E S, Dougherty P S M, Paley D W, Fred Higgs C, McGaughey A J H, Malen J A and Roy X 2017 Orientational order controls crystalline and amorphous thermal transport in superatomic crystals Nat. Mater. 16 83–88

[33] Cahill D G 2004 Analysis of heat flow in layered structures for time-domain thermoreflectance Rev. Sci. Instrum. 75 5119–22

[34] Chen N, Reeja-Jayan B, Liu A D, Lau J, Dunn B and Gleason K K 2016 iCVD cyclic polysiloxane and polysilazane as nanoscale thin-film electrolyte: synthesis and properties Macromol. Rapid Commun. 37 446–52

[35] Aresta G, Palmans J, van de Sanden M C M and Creatore M 2012 Initiated-chemical vapor deposition of organosilicon layers: monomer adsorption, bulk growth, and process window definition J. Vac. Sci. Technol. A 30 041503

[36] Grill A and Neumayer D A 2003 Structure of low dielectric constant to extreme low dielectric constant SiCOH films: Fourier transform infrared spectroscopy characterization J. Appl. Phys. 94 6697–707

[37] Burkey D D and Gleason K K 2004 Organosilicon thin films deposited from cyclic and acyclic precursors using water as an oxidant J. Electrochem. Soc. 151 F105

[38] Coclite A M, Ozaydin-Ince G, Palumbo F, Milella A and Gleason K K 2010 Single-chamber deposition of multilayer barriers by plasma enhanced and initiated chemical vapor deposition of organosilicones Plasma Process. Polym. 7 561–70

[39] Zhao J J, Wang M H and Gleason K K 2017 Stabilizing the wettability of initiated chemical vapor deposited (iCVD) polydivinylbenzene thin films by thermal annealing Adv. Mater. Interfaces 4 1700270

[40] Burkey D D and Gleason K K 2003 Structure and mechanical properties of thin films deposited from 1,3,5-trimethyl-1,3,5-trivinylcyclotrisiloxane and water J. Appl. Phys. 93 5143–50

[41] Oh T and Choi C K 2010 Comparison between SiOC thin film by plasma enhance chemical vapor deposition and SiO2 thin film by Fourier transform infrared spectroscopy J. Korean Phys. Soc. 56 1150–5

[42] ˇSimon I and McMahon H O 1953 Study of the structure of quartz, cristobalite, and vitreous silica by reflection in infrared J. Chem. Phys. 21 23–30

[43] O’Hare L-A, Hynes A and Alexander M R 2007 A methodology for curve-fitting of the XPS Si 2p core level from thin siloxane coatings Surf. Interface Anal. 39 926–36

[44] Roualdes S, Berjoan R and Durand J 2001 29Si NMR and Si2p XPS correlation in polysiloxane membranes prepared by plasma enhanced chemical vapor deposition Sep. Purif. Technol. 25 391–7

[45] Thorpe M F 1985 Rigidity percolation Physics of Disordered Materials ed D Adler, H Fritzsche and S R Ovshinsky (Boston: Springer) pp 55–61

[46] Phillips J C 1979 Topology of covalent non-crystalline solids I: short-range order in chalcogenide alloys J. Non-Cryst. Solids 34 153–81

[47] Thorpe M F 1983 Continuous deformations in random networks J. Non-Cryst. Solids 57 355–70

[48] QiuMJ,DuWW, LuoXY, ZhuSY, LuoYWandZhaoJJ 2022 Vapor-phase molecular doping in covalent organosiloxane network thin films via a Lewis acid–base interaction for enhanced mechanical properties ACS Appl. Mater. Interfaces 14 22719–27

[49] Kim B J, Seong H, Shim H, Lee Y I and Im S G 2017 Initiated chemical vapor deposition of polymer films at high process temperature for the fabrication of organic/inorganic multilayer thin film encapsulation Adv. Eng. Mater. 19 1600870

[50] Shen Y L 2019 Nanoindentation for testing material properties Handbook of Mechanics of Materials eds C H Hsueh, S Schmauder, C S Chen, K K Chawla, N Chawla, W Q Chen and Y Kagawa (Singapore: Springer) pp 1981–2012

[51] D.hler G H, Dandoloff R and Bilz H 1980 A topological-dynamical model of amorphycity J. Non-Cryst. Solids 42 87–95

[52] Ghossoub M G, Lee J-H, Baris O T, Cahill D G and Sinha S 2010 Percolation of thermal conductivity in amorphous fluorocarbons Phys. Rev. B 82 195441

[53] He H and Thorpe M F 1985 Elastic properties of glasses Phys. Rev. Lett. 54 2107–10

[54] Wen Q B, Yu Z J and Riedel R 2020 The fate and role of in situ formed carbon in polymer-derived ceramics Prog. Mater. Sci. 109 100623

[55] Schütz A, Günthner M, Motz G, Grei.l O and Glatzel U 2012 Characterisation of novel precursor-derived ceramic coatings with glass filler particles on steel substrates Surf. Coat. Technol. 207 319–27

[56] FengK,ChenY, DengPS,LiYY, ZhaoHX,Lu FG,LiRF, Huang J and Li Z G 2017 Improved high-temperature hardness and wear resistance of Inconel 625 coatings fabricated by laser cladding J. Mater. Process. Technol. 243 82–91

[57] Gridi O, Hamidouche Z M, Kermel C and Leriche A 2022 Mechanical and sandblasting erosion resistance characterization of chemical strengthened float glass Bol. Soc. Esp. Cerám. Vidr. 61 229–40

[58] Fellah M, Laba.z M, Assala O, Iost A and Dekhil L 2013 Tribological behaviour of AISI 316L stainless steel for biomedical applications Tribol. Mater. Surf. Interfaces 7 135–49

[59] Xu Y B, Wang H T, Tanaka Y, Shimono M and Yamazaki M 2007 Measurement of interfacial thermal resistance by periodic heating and a thermo-reflectance technique Mater. Trans. 48 148–50 ′

[60] Sandell S, Maire J, Chávez-Angel E, Sotomayor Torres C M, Kristiansen H, Zhang Z L and He J Y 2020 Enhancement of thermal boundary conductance of metal–polymer system Nanomaterials 10 670

[61] Jeong M, Freedman J P, Liang H J, Chow C-M, Sokalski V M, Bain J A and Malen J A 2016 Enhancement of thermal conductance at metal-dielectric interfaces using subnanometer metal adhesion layers Phys. Rev. Appl. 5 014009

[62] Eom J-H, Kim Y-W, Kim K J and Seo W-S 2018 Improved electrical and thermal conductivities of polysiloxane-derived silicon oxycarbide ceramics by barium addition J. Eur. Ceram. Soc. 38 487–93

[63] Mazo M A, Palencia C, Nistal A, Rubio F, Rubio J and Oteo J L 2012 Dense bulk silicon oxycarbide glasses obtained by spark plasma sintering J. Eur. Ceram. Soc. 32 3369–78

[64] Gurlo A, Ionescu E, Riedel R, Clarke D R and Green D J 2016 The thermal conductivity of polymer-derived amorphous Si–O–C compounds and nano-composites J. Am. Ceram. Soc. 99 281–5

[65] Cahill D G, Watson S K and Pohl R O 1992 Lower limit to the thermal conductivity of disordered crystals Phys. Rev. B 46 6131–40

[66] Agne M T, Hanus R and Snyder G J 2018 Minimum thermal conductivity in the context of diffuson-mediated thermal transport Energy Environ. Sci. 11 609–16

[67] Allen P B and Feldman J L 1993 Thermal conductivity of disordered harmonic solids Phys. Rev. B 48 12581–8

[68] Aryana K, Stewart D A, Gaskins J T, Nag J, Read J C, Olson D H, Grobis M K and Hopkins P E 2021 Tuning network topology and vibrational mode localization to achieve ultralow thermal conductivity in amorphous chalcogenides Nat. Commun. 12 2817