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    Journals >Journal of Inorganic Materials >Volume 36 >Issue 12 >Page 1247 > Article
    • Journal of Inorganic Materials
    • Vol. 36, Issue 12, 1247 (2021)
    Tailoring MAX Phase Magnetic Property Based on M-site and A-site Double Solid Solution
    Xiao ZHANG*, Youbing LI, Ke CHEN, Haoming DING..., Lu CHEN, Mian LI, Rongrong SHI, Zhifang CHAI and Qing HUANG|Show fewer author(s)
    DOI: 10.15541/jim20210126 Cite this Article
    Xiao ZHANG, Youbing LI, Ke CHEN, Haoming DING, Lu CHEN, Mian LI, Rongrong SHI, Zhifang CHAI, Qing HUANG. Tailoring MAX Phase Magnetic Property Based on M-site and A-site Double Solid Solution[J]. Journal of Inorganic Materials, 2021, 36(12): 1247 Copy Citation Text show less
    Characterization results of (V, Nb)2(Sn, Fe)C after acid treatment
    . Characterization results of (V, Nb)2(Sn, Fe)C after acid treatment
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    XRD patterns of (a) (V, Nb)2(Sn, Co)C, (c) (V, Nb)2(Sn, Ni)C, and (e) (V, Nb)2(Sn, Mn)C after acid treatment; SEM-EDS elemental mappings of (b) (V, Nb)2(Sn, Co)C, (d) (V, Nb)2(Sn, Ni)C, and (f) (V, Nb)2(Sn, Mn)C after acid treatment
    . XRD patterns of (a) (V, Nb)2(Sn, Co)C, (c) (V, Nb)2(Sn, Ni)C, and (e) (V, Nb)2(Sn, Mn)C after acid treatment; SEM-EDS elemental mappings of (b) (V, Nb)2(Sn, Co)C, (d) (V, Nb)2(Sn, Ni)C, and (f) (V, Nb)2(Sn, Mn)C after acid treatment
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    Temperature dependent magnetization M-T curves for (a) V2(Sn, A)C and (b) V2(Sn, A)C (A = Fe, Co, Ni and Mn) at 0.1 T in the range of 2-100 K
    . Temperature dependent magnetization M-T curves for (a) V2(Sn, A)C and (b) V2(Sn, A)C (A = Fe, Co, Ni and Mn) at 0.1 T in the range of 2-100 K
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    Magnetic hysteresis loops of V2(Sn, A)C and V2(Sn, A)C (A=Fe, Co, Ni and Mn) at different temperatures in the range from -1 to 1 T, respectively
    . Magnetic hysteresis loops of V2(Sn, A)C and V2(Sn, A)C (A=Fe, Co, Ni and Mn) at different temperatures in the range from -1 to 1 T, respectively
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    MAX phaseLattice parameterElement percentage/%Nb element in M site/% Magnetic element in A site/%
    a/nm c/nm c/aVNbSnA
    V2(Sn, Fe)C[23]0.29841.33454.471866.84-22.0511.11-33.50
    (V, Nb)2(Sn, Fe)C 0.30141.34474.462254.3213.3825.037.2719.7622.51
    V2(Sn, Co)C[23]0.29891.34094.486466.36-22.4411.19-33.28
    (V, Nb)2(Sn, Co)C 0.30161.34194.449356.4111.2324.607.7616.6023.98
    V2(Sn, Ni)C[23]0.29851.33574.475167.47-24.368.16-25.10
    (V, Nb)2(Sn, Ni)C 0.30211.34134.440256.8713.0021.668.4718.6128.10
    V2(Sn, Mn)C[23]0.29821.34034.494166.19-23.0710.74-31.76
    (V, Nb)2(Sn, Mn)C 0.30261.35094.464657.1010.8423.508.5615.9626.70
    Table 1. Lattice parameters and atomic percentage of element in MAX phases
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    MAX phaseTC2 K20 K40 K
    HcMrMsHcMrMsHcMrMs
    V2(Sn, Fe)C 634580.591.733050.421.531520.181.08
    (V, Nb)2(Sn, Fe)C 632380.481.791740.371.67730.141.24
    V2(Sn, Co)C 663140.341.192240.261.051130.120.79
    (V, Nb)2(Sn, Co)C 533780.491.112400.331.001340.170.71
    V2(Sn, Ni)C 602760.301.541910.231.42940.101.12
    (V, Nb)2(Sn, Ni)C 531400.292.07960.191.83450.071.34
    V2(Sn, Mn)C 567800.260.985450.210.842060.070.63
    (V, Nb)2(Sn, Mn)C 571170.060.97750.040.90320.010.67
    Table 2. Magnetic parameters of V2(Sn, A)C and (V, Nb)2(Sn, A)C (A = Fe, Co, Ni and Mn)
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    Xiao ZHANG, Youbing LI, Ke CHEN, Haoming DING, Lu CHEN, Mian LI, Rongrong SHI, Zhifang CHAI, Qing HUANG. Tailoring MAX Phase Magnetic Property Based on M-site and A-site Double Solid Solution[J]. Journal of Inorganic Materials, 2021, 36(12): 1247
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