• Chinese Optics Letters
  • Vol. 22, Issue 11, 113801 (2024)
Song Huang1, Anmin Wu1, Guanting Song2, Jiaxin Cao2..., Jianghong Yao2, Qiang Wu1,*, Weiqing Gao2,** and Jingjun Xu2|Show fewer author(s)
Author Affiliations
  • 1Department of Optical Engineering, School of Physics, Hefei University of Technology, Hefei 230601, China
  • 2Key Laboratory of Weak-Light Nonlinear Photonics, Ministry of Education, TEDA Institute of Applied Physics and School of Physics, Nankai University, Tianjin 300457, China
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    DOI: 10.3788/COL202422.113801 Cite this Article Set citation alerts
    Song Huang, Anmin Wu, Guanting Song, Jiaxin Cao, Jianghong Yao, Qiang Wu, Weiqing Gao, Jingjun Xu, "Titanium hyperdoped black silicon prepared by femtosecond laser irradiation: first-principle calculations and experimental verification," Chin. Opt. Lett. 22, 113801 (2024) Copy Citation Text show less
    Atomic configurations for (a) undoped crystal Si (Si64), (b) substitutional Ti-doped Si (TiSiSi63), and (c) interstitial Ti-doped Si (TiiSi64). The graphs below are the band structures for (d) Si64, (e) relaxed TiSiSi63, and (f) relaxed TiiSi64 compounds.
    Fig. 1. Atomic configurations for (a) undoped crystal Si (Si64), (b) substitutional Ti-doped Si (TiSiSi63), and (c) interstitial Ti-doped Si (TiiSi64). The graphs below are the band structures for (d) Si64, (e) relaxed TiSiSi63, and (f) relaxed TiiSi64 compounds.
    Optical absorption coefficients for the Si64, TiSiSi63, and TiiSi64 compounds.
    Fig. 2. Optical absorption coefficients for the Si64, TiSiSi63, and TiiSi64 compounds.
    (a) Absorptance spectra for the b-Si:Ti samples at different fluences and following RTA treatment at a temperature of 600°C. (b) Absorptance spectra for the b-Si:Ti samples (1.2 kJ/m2) before and after annealing under different temperatures, in which 25°C represents the unannealed sample of b-Si:Ti. The inset in (b) provides the variation in absorption at 1550 nm as a function of temperature.
    Fig. 3. (a) Absorptance spectra for the b-Si:Ti samples at different fluences and following RTA treatment at a temperature of 600°C. (b) Absorptance spectra for the b-Si:Ti samples (1.2 kJ/m2) before and after annealing under different temperatures, in which 25°C represents the unannealed sample of b-Si:Ti. The inset in (b) provides the variation in absorption at 1550 nm as a function of temperature.
    The obtained SEM images of the b-Si:Ti surface for different laser fluences at a rotation angle of 45° fabricated. (a) 1.2, (b) 2.5, (c) 4.5, and (d) 6.8 kJ/m2, whereas their corresponding high magnification images are presented in (e)–(h).
    Fig. 4. The obtained SEM images of the b-Si:Ti surface for different laser fluences at a rotation angle of 45° fabricated. (a) 1.2, (b) 2.5, (c) 4.5, and (d) 6.8 kJ/m2, whereas their corresponding high magnification images are presented in (e)–(h).
    (a) Raman spectra for the b-Si:Ti samples manufactured under different laser fluences and compared with Si substrate; (b) Raman spectra for the b-Si:Ti samples (1.2 kJ/m2) before annealing and after RTA treatment under different temperatures, in which 25°C represents an unannealed b-Si:Ti sample.
    Fig. 5. (a) Raman spectra for the b-Si:Ti samples manufactured under different laser fluences and compared with Si substrate; (b) Raman spectra for the b-Si:Ti samples (1.2 kJ/m2) before annealing and after RTA treatment under different temperatures, in which 25°C represents an unannealed b-Si:Ti sample.
    Song Huang, Anmin Wu, Guanting Song, Jiaxin Cao, Jianghong Yao, Qiang Wu, Weiqing Gao, Jingjun Xu, "Titanium hyperdoped black silicon prepared by femtosecond laser irradiation: first-principle calculations and experimental verification," Chin. Opt. Lett. 22, 113801 (2024)
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