• Journal of Inorganic Materials
  • Vol. 38, Issue 11, 1281 (2023)
Ya TANG1,2, Shengrui SUN2, Jia FAN1,2, Qingfeng YANG3..., Manjiang DONG2, Jiahui KOU1,* and Yangqiao LIU2,*|Show fewer author(s)
Author Affiliations
  • 11. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
  • 22. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • 33. Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
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    DOI: 10.15541/jim20230209 Cite this Article
    Ya TANG, Shengrui SUN, Jia FAN, Qingfeng YANG, Manjiang DONG, Jiahui KOU, Yangqiao LIU. PEI Modified Hydrated Calcium Silicate Derived from Fly Ash and Its adsorption for Removal of Cu (II) and Catalytic Degradation of Organic Pollutants[J]. Journal of Inorganic Materials, 2023, 38(11): 1281 Copy Citation Text show less
    EDS analyses of CSH
    S1. EDS analyses of CSH
    (a) XRD patterns, (b) FT-IR spectra and (c) N2 adsorption-desorption isotherms of CSH and PCSH
    1. (a) XRD patterns, (b) FT-IR spectra and (c) N2 adsorption-desorption isotherms of CSH and PCSH
    Different magnification SEM images of (a, b) CSH and (c, d) PCSH
    2. Different magnification SEM images of (a, b) CSH and (c, d) PCSH
    EDS analysis of PCSH
    S2. EDS analysis of PCSH
    Linear fitting curves of (a) Langmuir model and (b) Freundlich model for isotherms of CSH and PCSH
    S3. Linear fitting curves of (a) Langmuir model and (b) Freundlich model for isotherms of CSH and PCSH
    Adsorption characteristics of samples
    3. Adsorption characteristics of samples
    EDS analyses of PCSH-Cu
    S4. EDS analyses of PCSH-Cu
    Characteristics of Cu-absorbed samples
    4. Characteristics of Cu-absorbed samples
    SEM images of (a) CSH-Cu, (b) PCSH-Cu, (c) CSH- Cu-c, and (d) PCSH-Cu-c
    5. SEM images of (a) CSH-Cu, (b) PCSH-Cu, (c) CSH- Cu-c, and (d) PCSH-Cu-c
    (a) XRD patterns and (b) FT-IR spectra of CSH-Cu-c and PCSH-Cu-c
    6. (a) XRD patterns and (b) FT-IR spectra of CSH-Cu-c and PCSH-Cu-c
    Degradation of RhB by PMS with CSH-Cu-c and PCSH-Cu-c
    7. Degradation of RhB by PMS with CSH-Cu-c and PCSH-Cu-c
    Suface elements and chemical status of samples
    8. Suface elements and chemical status of samples
    Free radical capture experiments of PCSH-Cu-c
    9. Free radical capture experiments of PCSH-Cu-c
    Change of 4-NP residue percentage
    10. Change of 4-NP residue percentage
    CatalystC1/(g·L-1) CPMS/(g·L-1) CRhB/(mg·L-1) k/min-1Ref.
    MPC10.616200.013[27]
    α-MnO2/Pal0.10.1200.0204[28]
    Vis/BiVO40.50.616100.04[29]
    rGO-CoPc0.30.616100.288[30]
    CSH-Cu-c0.80.12200.036This work
    PCSH-Cu-c0.80.12200.7135This work
    Table 1. Rate constants (k) for the degradation of RhB by PMS with different catalysts
    SampleLangmuir modelFreundlich model
    qmKLR2nKFR2
    CSH294.100.02000.99453.81054.000.8670
    PCSH588.230.05630.99825.848198.860.9450
    Table 1. Langmuir and Freundlich isotherm fitting parameters
    Sampleq / (mg·g-1) SBET/ (m2·g-1) Ref.
    Activated carbon10921[S1]
    Modified SBA-15 mesoporous silica46317[S2]
    MCM-48126511[S3]
    Citrate-LDH1378[S4]
    Mesoporous silica153462[S5]
    Humulus scandens-derived biochars221450[S6]
    Steel slag-derived CSH24477[S7]
    Amorphous molybdenum sulphide25928[S8]
    NPCS-PEI276491[S9]
    CSH294240This work
    PCSH588371This work
    Table 2. Comparison of maximum adsorption capacities of various sorbents as reported in the literature for Cu(II)
    CatalystC1/(g·L-1) CNaBH4/(mmol·L-1) C4-NP/(mmol·L-1) k/(×10-3,s-1) Ref.
    CuO NLs0.307100.120.36[38]
    Ag-NP/C0.3336.6674.7×10-21.69[39]
    Cu2−xSe/rGO/PVP2.562.50.1252.3[40]
    Pd-FG0.5100.12.35[41]
    CSH-Cu-c0.16750.10.61This work
    PCSH-Cu-c0.16750.111.47This work
    Table 2. Rate constants (k) for the degradation of 4-NP by NaBH4 with different catalysts
    Ya TANG, Shengrui SUN, Jia FAN, Qingfeng YANG, Manjiang DONG, Jiahui KOU, Yangqiao LIU. PEI Modified Hydrated Calcium Silicate Derived from Fly Ash and Its adsorption for Removal of Cu (II) and Catalytic Degradation of Organic Pollutants[J]. Journal of Inorganic Materials, 2023, 38(11): 1281
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