• Spectroscopy and Spectral Analysis
  • Vol. 42, Issue 2, 410 (2022)
Yao-qiang HU1,*, Min GUO2,2;, Xiu-shen YE2,2;, Quan LI2,2;..., Hai-ning LIU2,2; *; and Zhi-jian WU2,2;|Show fewer author(s)
Author Affiliations
  • 11. College of Ocean and Meteorology, Guangdong Ocean University, Zhanjiang 524088, China
  • 22. Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt Lakes, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
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    DOI: 10.3964/j.issn.1000-0593(2022)02-0410-05 Cite this Article
    Yao-qiang HU, Min GUO, Xiu-shen YE, Quan LI, Hai-ning LIU, Zhi-jian WU. Indirect Determination of Liquor Alcohol Content Based on Near-Infrared Spectrophotometry[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 410 Copy Citation Text show less
    Effect of optical distance on ultraviolet-visible-near infrared spectral images of water
    Fig. 1. Effect of optical distance on ultraviolet-visible-near infrared spectral images of water
    Effect of optical distance on ultraviolet-visible-near infrared spectral images of ethanol
    Fig. 2. Effect of optical distance on ultraviolet-visible-near infrared spectral images of ethanol
    Near-infrared spectral images of ethanol aqueous solutions
    Fig. 3. Near-infrared spectral images of ethanol aqueous solutions
    Absorbance fitting curves of ethanol aqueous solutions at 1 448 nm(a): 0~100%; (b): 20%~80%
    Fig. 4. Absorbance fitting curves of ethanol aqueous solutions at 1 448 nm
    (a): 0~100%; (b): 20%~80%
    Absorption spectra of some brand liquors (a) and bulk liquors (b)
    Fig. 5. Absorption spectra of some brand liquors (a) and bulk liquors (b)
    Optical
    distance/mm
    Absorbance
    ( 1448 nm)
    κ/
    (L·mol-1·cm-1)
    11.4030.253
    22.9800.269
    10>10 (Invalid value)-
    Table 1. Absorbances of water at 1 448 nm with different optical distances
    ReagentOptical
    distance/mm
    Absorbance
    (1 448 nm)
    κ/
    (L·mol-1·cm-1)
    Ethanol10.1160.067 8
    101.3300.077 7
    Table 2. Absorbances of ethanol at 1 448 nm with different optical distances
    Mass ratio of ethanol/%Absorbance (1 448 nm)
    01.403
    101.255
    201.121
    300.987
    400.857
    500.697
    600.574
    700.443
    800.297
    900.206
    1000.118
    Table 3. Absorbances of ethanol aqueous solutions with different mass ratios at 1 448 nm
    A (1 448 nm)0.118 90.118 80.118 90.118 80.118 90.118 9
    Table 4. Absorbance values of ethanol obtained by measurement repeated 6 times
    BrandA
    (1 448 nm)
    Reference
    value
    /(%Vol)
    Measured
    value
    (%Vol)
    Relative
    Deviation
    brand 10.96040%38%-5.0%
    brand 20.90043%43%0%
    brand 30.87845%45%0%
    brand 40.77253%54%1.9%
    brand 50.75654%55%1.9%
    bulk 11.01842%33%-21.4%
    bulk 20.88345%45%0%
    bulk 30.89148%44%-8.3%
    bulk 40.80550%51%2.0%
    bulk 50.75553%55%3.8%
    Table 5. Predicted results of verified sample
    Yao-qiang HU, Min GUO, Xiu-shen YE, Quan LI, Hai-ning LIU, Zhi-jian WU. Indirect Determination of Liquor Alcohol Content Based on Near-Infrared Spectrophotometry[J]. Spectroscopy and Spectral Analysis, 2022, 42(2): 410
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