Gaoran LI, Hongyang LI, Haibo ZENG. Recent Progress of Boron-based Materials in Lithium-sulfur Battery [J]. Journal of Inorganic Materials, 2022, 37(2): 152

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- Journal of Inorganic Materials
- Vol. 37, Issue 2, 152 (2022)
![Schematic diagram of (a) lithium-sulfur battery configuration and (b) corresponding charge-discharge process[7]](/richHtml/jim/2022/37/2/152/img_1.png)
1. Schematic diagram of (a) lithium-sulfur battery configuration and (b) corresponding charge-discharge process[7]
![(a) Structural models of different borophenes and their corresponding charge density distributions, (b) adsorption energies of polysulfides on different borophenes[25]](/richHtml/jim/2022/37/2/152/img_2.png)
2. (a) Structural models of different borophenes and their corresponding charge density distributions, (b) adsorption energies of polysulfides on different borophenes[25]
![(a) Scheme of B-doped carbon backbone, (b) S2p XPS spectra of sulfur composites based on different element-doped porous carbon; and (c) scheme of charge-discharge process of NBCGN/S composite, (d) cycling at 0.2C and (e) rate performances of sulfur electrodes based on different element-doped curved graphene nanoribbons[44]](/Images/icon/loading.gif)
3. (a) Scheme of B-doped carbon backbone, (b) S2p XPS spectra of sulfur composites based on different element-doped porous carbon; and (c) scheme of charge-discharge process of NBCGN/S composite, (d) cycling at 0.2C and (e) rate performances of sulfur electrodes based on different element-doped curved graphene nanoribbons[44]
![Conductivity comparison with several categories of metal compounds[48,49,50,51,52,53,54,55,56]](/Images/icon/loading.gif)
![(a) Li2S4 adsorption configurations on Co2B and Co2B@MXene surfaces, (b) scheme of the electron redistribution at the interfaces between Co2B and MXene, (c) cycling performances of cells based on Co2B@MXene and other separators, (d) long-term cycling performance of the Co2B@MXene cell[63]; (e) schematic illustration of surface-chemical entrapment of polysulfides on TiB2, (f) adsorption configurations and (g) energies of sulfur species on (001) and (111) surfaces of TiB2, (h) high-loading performance and (i) long-term cycling of TiB2-based sulfur electrode[63,65]](/Images/icon/loading.gif)
5. (a) Li2S4 adsorption configurations on Co2B and Co2B@MXene surfaces, (b) scheme of the electron redistribution at the interfaces between Co2B and MXene, (c) cycling performances of cells based on Co2B@MXene and other separators, (d) long-term cycling performance of the Co2B@MXene cell[63]; (e) schematic illustration of surface-chemical entrapment of polysulfides on TiB2, (f) adsorption configurations and (g) energies of sulfur species on (001) and (111) surfaces of TiB2, (h) high-loading performance and (i) long-term cycling of TiB2-based sulfur electrode[63,65]
![(a) TEM image and schematic atomic structure of v-BN[78]; (b) Scheme of g-C3N4/BN/graphene composite ion-sieve and (c) the corresponding Li-S cell cycling performance[80]; (d) Schematic and optical image of BN/Celgard/carbon trilayer separator, and (e) the corresponding cell cycling performance[83]; (f) Scheme and (g) SEM image of B4C@CNF and the model of B4C nanowire, (h) Li2S4 adsorption energies on different facets of B4C[87]](/Images/icon/loading.gif)
6. (a) TEM image and schematic atomic structure of v-BN[78]; (b) Scheme of g-C3N4/BN/graphene composite ion-sieve and (c) the corresponding Li-S cell cycling performance[80]; (d) Schematic and optical image of BN/Celgard/carbon trilayer separator, and (e) the corresponding cell cycling performance[83]; (f) Scheme and (g) SEM image of B4C@CNF and the model of B4C nanowire, (h) Li2S4 adsorption energies on different facets of B4C[87]

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