• Journal of Inorganic Materials
  • Vol. 37, Issue 5, 547 (2022)
Hongli WANG1, Nan WANG1, Liying WANG1, Erhong SONG2,*, and Zhankui ZHAO1,*
Author Affiliations
  • 11. Key Laboratory of Advanced Structural Materials, Ministry of Education, School of Materials Science and Engineering, Changchun University of Technology, Changchun 130012, China
  • 22. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
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    DOI: 10.15541/jim20210311 Cite this Article
    Hongli WANG, Nan WANG, Liying WANG, Erhong SONG, Zhankui ZHAO. Hydrogen Generation from Formic Acid Boosted by Functionalized Graphene Supported AuPd Nanocatalysts[J]. Journal of Inorganic Materials, 2022, 37(5): 547 Copy Citation Text show less
    TEM images, XRD pattern and EDX spectrum of Au0.3Pd0.7/PEI-rGO
    2. TEM images, XRD pattern and EDX spectrum of Au0.3Pd0.7/PEI-rGO
    XPS spectra of Au0.3Pd0.7/PEI-rGO and Au0.3Pd0.7/rGO
    3. XPS spectra of Au0.3Pd0.7/PEI-rGO and Au0.3Pd0.7/rGO
    Comparison of the catalytic performances for hydrogen evolution from FA dehydrogenation reaction of Au0.3Pd0.7/PEI-rGO, Au0.3Pd0.7/rGO and Au0.3Pd0.7 catalysts
    4. Comparison of the catalytic performances for hydrogen evolution from FA dehydrogenation reaction of Au0.3Pd0.7/PEI-rGO, Au0.3Pd0.7/rGO and Au0.3Pd0.7 catalysts
    (a) Volume of gas versus time for the dehydrogenation of FA at different temperatures over Au0.3Pd0.7/PEI-rGO catalyst; (b) Arrhenius plot (lnTOF versus 1/T) for Au0.3Pd0.7/PEI-rGO; (c) Volume of gas versus time for the dehydrogenation of FA at different ratios of AuxPd1-x/PEI-rGO (x=0, 0.1, 0.3, 0.7, 0.9, 1.0) at 323 K; (d) Durability tests of Au0.3Pd0.7/PEI-rGO towards the decomposition of FA (1.0 mol/L, 5.0 mL)
    5. (a) Volume of gas versus time for the dehydrogenation of FA at different temperatures over Au0.3Pd0.7/PEI-rGO catalyst; (b) Arrhenius plot (lnTOF versus 1/T) for Au0.3Pd0.7/PEI-rGO; (c) Volume of gas versus time for the dehydrogenation of FA at different ratios of AuxPd1-x/PEI-rGO (x=0, 0.1, 0.3, 0.7, 0.9, 1.0) at 323 K; (d) Durability tests of Au0.3Pd0.7/PEI-rGO towards the decomposition of FA (1.0 mol/L, 5.0 mL)
    CatalystTemperature/Kncatalyst/nFATOF/(molH2∙ molcatalyst-1∙h-1)
    Pd-NPs@TA-CoP[22]3280.013233.0a
    Pd@ED/Cr-MIL-101[23]3280.003583.0b
    Ni0.4Pd0.6/NH2-N-rGO[10]2980.020954.3a
    Pd0.7Ag0.3/CeOx-NPC[24]3230.0081101.9a
    Pd@TB-POP[7]3230.1001344.0b
    Pd/ImIP-2[25]3230.0081593.0b
    AuPd/n-CNS[26]3330.0201896.0a
    PdAg-CeO2[27]3030.0332272.8a
    Au0.3Pd0.7/PEI-rGO3230.0202357.5a
    Pd/MSC-30[28]3230.0132623.0a
    Pd-Co2P/NPC[13]3230.0262980.0b
    Table 1. TOF of different catalysts for FA dehydrogenation
    Hongli WANG, Nan WANG, Liying WANG, Erhong SONG, Zhankui ZHAO. Hydrogen Generation from Formic Acid Boosted by Functionalized Graphene Supported AuPd Nanocatalysts[J]. Journal of Inorganic Materials, 2022, 37(5): 547
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