Bo MENG, Gang XIAO, Xiuli WANG, Jiangping TU, Changdong GU. Ionic Thermal Synthesis and Reversible Heat Storage Performance of Manganese-based Oxides [J]. Journal of Inorganic Materials, 2023, 38(7): 793

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- Journal of Inorganic Materials
- Vol. 38, Issue 7, 793 (2023)

1. Redox reaction characteristics of Mn2O3 by ionic thermal synthesis and commercial Mn2O3

2. (a-d) SEM images of samples before and after cycling, and (e) O1s XPS spectra of Mn2O3 before cycling

3. Redox reaction of samples with different Fe contents

4. (a) TG curves and (b) oxidation reaction conversion rate-time curves of samples prepared at different ionic thermal synthesis temperatures

5. SEM images of samples prepared by ionic thermal synthesis at different temperatures before cycling

6. (a) Thermochemical heat storage density and (b) thermal cycling curves of 150 ℃-4 h

7. O1s XPS spectra of 150 ℃-4h

8. Characterization of precursors of manganese-based oxide synthesized by DES

9. Formation process of heat storage materials induced by

S1. Photos of DES

S2. DSC curve of Mn2O3 by ionic thermal synthesis

S3. TG curves of (Mn0.8Fe0.2)2O3 by solid-phase and ionic thermal synthesis

S4. XRD patterns of samples after heat treatment under different temperatures prepared by MnCl2/Urea DES

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