• Journal of Inorganic Materials
  • Vol. 37, Issue 5, 554 (2022)
Zhijun CAO and Zaijun LI*
Author Affiliations
  • School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
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    DOI: 10.15541/jim20210365 Cite this Article
    Zhijun CAO, Zaijun LI. Ruthenium-biocarbon Mimic Enzyme: Synthesis and Application in Colorimetric Detection of Pesticide Chlorpyrifos[J]. Journal of Inorganic Materials, 2022, 37(5): 554 Copy Citation Text show less
    SEM (A), TEM (B), HRTEM images (C), and elemental mappings of Ru (D) and N (E) elements and XRD pattern (F) of the as-prepared Ru-biomass carbon composite
    1. SEM (A), TEM (B), HRTEM images (C), and elemental mappings of Ru (D) and N (E) elements and XRD pattern (F) of the as-prepared Ru-biomass carbon composite
    Total XPS spectrum (A), high-resolution C1s (B), Ru3p (C) and N1s (D) XPS spectra of Ru-biomass carbon composite
    2. Total XPS spectrum (A), high-resolution C1s (B), Ru3p (C) and N1s (D) XPS spectra of Ru-biomass carbon composite
    Absorption spectra of the reaction system catalysis by Ru-biomass carbon composite (a), CuO/Pt composite (b), Ru nanoparticles (c), and biomass carbon (d)
    3. Absorption spectra of the reaction system catalysis by Ru-biomass carbon composite (a), CuO/Pt composite (b), Ru nanoparticles (c), and biomass carbon (d)
    Absorbances at 665 nm of the N2, air and O2 saturated TMB solutions with catalysis by Ru-biomass carbon composite
    4. Absorbances at 665 nm of the N2, air and O2 saturated TMB solutions with catalysis by Ru-biomass carbon composite
    Relationship curves of pH (A), reaction time (B), reaction temperature (C), and catalyst amount (D) with the absorbance of the reaction system
    5. Relationship curves of pH (A), reaction time (B), reaction temperature (C), and catalyst amount (D) with the absorbance of the reaction system
    Absorption spectra of the reaction system in the presence of 0, 10, 20, 30, 40, 50, 60, 70 and 80 ng/mL chlorpyrifos (A) and calibration plot of the absorbance at 665 nm varied with the chlorpyrifos concentration (B)
    6. Absorption spectra of the reaction system in the presence of 0, 10, 20, 30, 40, 50, 60, 70 and 80 ng/mL chlorpyrifos (A) and calibration plot of the absorbance at 665 nm varied with the chlorpyrifos concentration (B)
    Chromogenic systemAnalysis time/minLinear range/(ng·mL-1)Detection limit/(ng·mL-1)Ref.
    Gold nanoclusters401500-450006000[23]
    Acetylcholine5510000-1400004000[24]
    Cu-Ag/rGO30300-90001080[25]
    Hemin regulated by oligonucleotide622000-100000600[26]
    CuO/Pt50300-180000238.8[19]
    Fe-N-C76100-1000097[27]
    Cu NPs10300-300020.4[28]
    Ru-biomass carbon composite205-806.57This work
    Table 1. Comparison of colorimetric methods with different nanozyme materials for detection of organophosphorus pesticides
    SampleChlorpyrifos added/(ng·mL-1)Chlorpyrifos detected by proposed method/(ng·mL-1)Chlorpyrifos founded by GC-MS/(ng·mL-1)Recovery/%
    Honey peach0(5.9±0.15)(6.02±0.12)
    10.0(16.2±0.18)(16.05±0.10)101.8
    Nectarine0(9.98±0.07)(9.95±0.07)
    10.0(19.91±0.27)(20.1±0.27)99.6
    Peento0(4.96±0.11)(5.07±0.05)
    10.0(15.2±0.19)(15.07±0.25)101.6
    Table 2. Results for detection of chlorpyrifos in peach (n=5)
    Zhijun CAO, Zaijun LI. Ruthenium-biocarbon Mimic Enzyme: Synthesis and Application in Colorimetric Detection of Pesticide Chlorpyrifos[J]. Journal of Inorganic Materials, 2022, 37(5): 554
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