Planar Na ion micro-supercapacitors (NIMSCs) that offer both high energy density and power density are deemed to a promising class of miniaturized power sources for wearable and portable microelectronics. Nevertheless, the development of NIMSCs are hugely impeded by the low capacity and sluggish Na ion kinetics in the negative electrode. Herein, we demonstrate a novel carbon-coated Nb2O5 microflower with a hierarchical structure composed of vertically intercrossed and porous nanosheets, boosting Na ion storage performance. The unique structural merits, including uniform carbon coating, ultrathin nanosheets and abundant pores, endow the Nb2O5 microflower with highly reversible Na ion storage capacity of 245 mAh g-1 at 0.25 C and excellent rate capability. Benefiting from high capacity and fast charging of Nb2O5 microflower, the planar NIMSCs consisted of Nb2O5 negative electrode and activated carbon positive electrode deliver high areal energy density of 60.7 μWh cm-2, considerable voltage window of 3.5 V and extraordinary cyclability. Therefore, this work exploits a structural design strategy towards electrode materials for application in NIMSCs, holding great promise for flexible microelectronics.