[1] Sorokin G P, Papshev Y M, Oush P T. Photoconductivity of Cu2 S, Cu2 Se and Cu2 Te ［J］. Sov. Phys. Solid State, 1966, 7(8): 1810-1813.

[2] Sankapal B R, Mane R S, Lokhande C D. Preparation and characterization of Bi2 Se3 thin films deposited by successive ionic layer adsorption and reaction (SILAR) method ［J］. Mater. Chem. Phys., 2000, 63(3): 230-234.

[3] Black J, Conwell E M, Seigle L, et al. Electrical and optical properties of some M2 -N3 semiconductors ［J］. J. Phys. Chem. Solids, 1957, 2(3): 240-251.

[4] Wu Zhengcui, Pan Cheng, Yao Zhenyu, et al. Large-scale synthesis of single-crystal double-fold snowflake Cu2 S dendrites ［J］. Cryst. Growth Des., 2006, 6(7): 1717-1719.

[5] Romanyuk Y E, Parasyuk O V. Phase equilibria in the quasi-ternary Cu2 Se-ZnSe-GeSe2 system ［J］. J. Alloys Compd., 2003, 348(1-2): 195-202.

[6] Cui Hongmei, Liu Hong, Li Xia, et al. Synthesis of Bi2 Se3 thermoelectric nanosheets and nanotubes through hydrothermal co-reduction method ［J］. J. Solid State Chem., 2004, 177(11): 4001-4006.

[7] Yuhachi N, Yoshio N, Mitsuo S. Electrical conductivity and thermoelectric power of some molten AIBIIICVI2 and AIBVCVI2 compounds ［J］. J. of Non-crystalline Solids, 1975, 17(2): 231-240.

[8] Berger L I, Prochukan V D. Ternary Diamond-Like Semiconductors ［M］. New York: Consultant Bureau Enterprises Inc., 1969: 47-49.

[9] Zhuze V P, Sergeeva V M, Shtrum E L. Semiconducting compounds with the general formula ABX2 ［J］. Sov. Phys. Tech. Phys., 1958, 3: 1925-1938.

[10] Bastow T J, Whiteld H J. NQR study of ternary chalcogenides A3 BX［Trial mode］, ABX［Trial mode］, and ABX where A=Cu, Ag, or TI, B=As or Sb, and X=S or Se ［J］. J. Solid State Chem., 1981, 40(2): 203-209.

[11] Manolache S, Duta A, Isac L, et al. The influence of the precursor concentration on CuSbS［Trial mode］ thin films deposited from aqueous solutions ［J］. Thin Solid Films, 2007, 515(15): 5957-5960.

[12] Sugaki A, Shima H. The phase equilibrium study of the Cu-Bi-S system ［C］. Proc. IMA-IAGOD Meeting, 1971, 70: 270-271.

[13] Sugaki A, Shima H. Phase relations of the Cu［Trial mode］S-Bi［Trial mode］S［Trial mode］ system ［R］. Technol. Rept., Yamaguchi Univ., 1972, 1: 45-70.

[14] Wang Naiding. The Cu-Bi-S system: results from low-temperature experiments ［J］. Minera. Mag., 1994, 58(2): 201-204.

[15] Garcia J C, Brun G, Liautard B, et al. Etude des equilibres de phases dans le systeme Cu［Trial mode］Se-Bi［Trial mode］Se［Trial mode］ Caracterisation des composes intermediaries ［J］. Mater. Res. Bull., 1990, 25(2): 241-249.

[16] Liautard B, Garcia J C, Brun G, et al. Crystal structure of Cu［Trial mode］Bi［Trial mode］X［Trial mode］ (X=S, Se) alloys ［J］. J. Solid State Inorg. Chem., 1990, 25(2): 819-830.

[17] Van Arkel A E, Crevecoeur C. Quelques sulfures et séléniures complexes ［J］. J. Less-Common Met., 1963, 5(2): 177-180.

[18] Su Huilan, Xie Yi, Wan Shoukang, et al. A novel one-step solvothermal route to nanocrystalline CuSbS［Trial mode］ and Ag［Trial mode］SbS［Trial mode］ ［J］. Solid State Ionics, 1999, 123(1-4): 319-324.

[19] An Changhua, Liu Qiangchun, Tang Kaibin, et al. The influences of surfactant concentration on the quality of chalcostibite nanorods ［J］. J. Cryst. Growth, 2003, 256(1-2): 128-133.

[20] Powell A V, Raquel P, Paz V, et al. An antimony sulfide with copper pillars: ［C［Trial mode］H［Trial mode］N［Trial mode］］［Trial mode］［CuSb［Trial mode］S［Trial mode］］ ［J］. Chem. Mater., 2002, 14(3): 1220-1224.

[23] Li Qi, Zhang Shiwei, et al. Magnetic properties in a partially oxidized nanocomposite of Cu-CuCl ［J］. Nanotechnology, 2006, 17(19): 4981-4985.

[24] ［t］ 16cm Wu P, Steven R H, Anh T D, et al. A sol-gel solid electrolyte with high lithium ion conductivity ［J］. Chem. Mater., 1997, 9(4): 1004-1011.

[25] ［t］ 16cm Rabenau A, Rau H. Spectral reflectance measurements on ternary compounds of copper with group VI and VII elements ［J］. Solid State Commun., 1969, 7(17): 1281-1282.