• Journal of Radiation Research and Radiation Processing
  • Vol. 41, Issue 5, 050203 (2023)
Wanfeng HONG1, Fan ZHANG2, Wanning REN3, Zhi XIONG2..., Yarui AN1, Wenli ZHANG2,* and Guozhong WU2,3,**|Show fewer author(s)
Author Affiliations
  • 1University of Shanghai Science and Technology, Shanghai 200093, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3ShanghaiTech University, Shanghai 200031, China
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    DOI: 10.11889/j.1000-3436.2022-0123 Cite this Article
    Wanfeng HONG, Fan ZHANG, Wanning REN, Zhi XIONG, Yarui AN, Wenli ZHANG, Guozhong WU. Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(5): 050203 Copy Citation Text show less
    FTIR spectra of the P(AN-co-IA)samples (a) and partial enlarged image (b) (color online)
    Fig. 1. FTIR spectra of the P(AN-co-IA)samples (a) and partial enlarged image (b) (color online)
    Content of IA as a function of ratio of intensities of-COOH to-C≡N
    Fig. 2. Content of IA as a function of ratio of intensities of-COOH to-C≡N
    Different samples were heat treated at 220 ℃ for 30 min: (a) FTIR spectra of P0~P5 samples; (b) FTIR spectra of P0~P5 samples after pretreatment with an absorbed dose of 75 kGy; (c) FTIR spectra of P3 samples after irradiation with different absorbed doses; (d) EOR result chart of all samples
    Fig. 3. Different samples were heat treated at 220 ℃ for 30 min: (a) FTIR spectra of P0~P5 samples; (b) FTIR spectra of P0~P5 samples after pretreatment with an absorbed dose of 75 kGy; (c) FTIR spectra of P3 samples after irradiation with different absorbed doses; (d) EOR result chart of all samples
    DSC curves of P(AN-co-IA)powder irradiated at various doses in nitrogen atmosphere(a) 0 kGy; (b) 25 kGy; (c) 50 kGy; (d) 75 kGy; (e) 100 kGy; (f) 200 kGy
    Fig. 4. DSC curves of P(AN-co-IA)powder irradiated at various doses in nitrogen atmosphere(a) 0 kGy; (b) 25 kGy; (c) 50 kGy; (d) 75 kGy; (e) 100 kGy; (f) 200 kGy
    DSC results of samples with different absorbed doses and IA contents: (a) released heat; (b) difference between initiation temperature and termination temperature; (c) velocity of releasing heat
    Fig. 5. DSC results of samples with different absorbed doses and IA contents: (a) released heat; (b) difference between initiation temperature and termination temperature; (c) velocity of releasing heat
    Influence coefficient of two modification methods on the cyclization reaction of P(AN-co-IA)
    Fig. 6. Influence coefficient of two modification methods on the cyclization reaction of P(AN-co-IA)
    TG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 100 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
    Fig. 7. TG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 100 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
    DTG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 75 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
    Fig. 8. DTG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 75 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)

    聚合物

    Polymer

    丙烯腈 / mL

    AN

    丙烯腈 / g

    AN

    衣康酸 / g

    IA

    IA质量分数 / %

    IA mass fraction

    过硫酸铵 / g

    APS

    转化率 / %

    Conversion ratio

    P041.033.00000.3390.33
    P140.532.600.330 21.00.3391.14
    P240.332.450.495 01.50.3389.98
    P340.132.300.660 12.00.3390.60
    P439.732.100.990 23.00.3389.70
    P539.331.681.320 64.00.3391.35
    Table 1. Aggregate acquired PAN-co-IA samples
    Wanfeng HONG, Fan ZHANG, Wanning REN, Zhi XIONG, Yarui AN, Wenli ZHANG, Guozhong WU. Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(5): 050203
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