Wanfeng HONG, Fan ZHANG, Wanning REN, Zhi XIONG, Yarui AN, Wenli ZHANG, Guozhong WU. Synergistic effect of itaconic acid and irradiation modification on cyclization of polyacrylonitrile[J]. Journal of Radiation Research and Radiation Processing, 2023, 41(5): 050203

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Journals >Journal of Radiation Research and Radiation Processing >Volume 41 >Issue 5 >Page 050203 > Article
- Journal of Radiation Research and Radiation Processing
- Vol. 41, Issue 5, 050203 (2023)

Fig. 1. FTIR spectra of the P(AN-co-IA)samples (a) and partial enlarged image (b) (color online)

Fig. 2. Content of IA as a function of ratio of intensities of-COOH to-C≡N

Fig. 3. Different samples were heat treated at 220 ℃ for 30 min: (a) FTIR spectra of P0~P5 samples; (b) FTIR spectra of P0~P5 samples after pretreatment with an absorbed dose of 75 kGy; (c) FTIR spectra of P3 samples after irradiation with different absorbed doses; (d) EOR result chart of all samples

Fig. 4. DSC curves of P(AN-co-IA)powder irradiated at various doses in nitrogen atmosphere(a) 0 kGy; (b) 25 kGy; (c) 50 kGy; (d) 75 kGy; (e) 100 kGy; (f) 200 kGy

Fig. 5. DSC results of samples with different absorbed doses and IA contents: (a) released heat; (b) difference between initiation temperature and termination temperature; (c) velocity of releasing heat

Fig. 6. Influence coefficient of two modification methods on the cyclization reaction of P(AN-co-IA)

Fig. 7. TG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 100 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)

Fig. 8. DTG curves of a part of powder samples heated at 10 ℃/min: (a) not irradiated by electron beam; (b) irradiated by 75 kGy electron beam; (c) irradiated by 150 kGy electron beam; (d) P3 samples irradiated by electron beam with different absorbed doses(color online)
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Table 1. Aggregate acquired P (AN-co-IA ) samples

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