Researching | Preparation of amidoxime-based adsorption materials with a multi-amino synergistic effect and their uranium adsorption performance

Journals >Journal of Radiation Research and Radiation Processing >Volume 42 >Issue 2 >Page 020202 > Article

Journal of Radiation Research and Radiation Processing
Vol. 42, Issue 2, 020202 (2024)

Preparation of amidoxime-based adsorption materials with a multi-amino synergistic effect and their uranium adsorption performance

Wanning REN¹, Xinxin FENG^2、3, Hongwei HAN⁴, Jiangtao HU^2、*, and Guozhong WU^1、2、**

Author Affiliations

¹ShanghaiTech University, Shanghai 200031, China

²Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China

³University of Chinese Academy of Sciences, Beijing 100049, China

⁴Shanghai University, Shanghai 200444, China

show less

DOI: 10.11889/j.1000-3436.2023-0061 Cite this Article

Wanning REN, Xinxin FENG, Hongwei HAN, Jiangtao HU, Guozhong WU. Preparation of amidoxime-based adsorption materials with a multi-amino synergistic effect and their uranium adsorption performance[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(2): 020202 Copy Citation Text

show less

Synthesis route of P-TETA-AO, P-TEPA-AO, and P-PEHA-AO

Fig. 1. Synthesis route of P-TETA-AO, P-TEPA-AO, and P-PEHA-AO

Download full size | View in the Article

Synthesis reaction formula of P-TETA, P-TEPA, and P-PEHA

Fig. 2. Synthesis reaction formula of P-TETA, P-TEPA, and P-PEHA

Download full size | View in the Article

Fig. 3. Synthesis reaction formula of P-TETA-AN, P-TEPA-AN, and P-PEHA-AN

Download full size | View in the Article

Fig. 4. ATR-FTIR spectra of the material before and after modification

Download full size | View in the Article

Fig. 5. SEM images of pristine PP/PE SNW, and P-TETA-AO, P-TEPA-AO, P-PEHA-AO before and after uranium absorption(a~g), image on color changes of three kinds of adsorption materials before and after uranium adsorption (h) (color onlinr)

Download full size | View in the Article

Fig. 6. (a) TG and (b) DTG curves of pristine PP/PE SNW, P-TETA-AO-U, P-TEPA-AO-U, and P-PEHA-AO-U (color online)

Download full size | View in the Article

Fig. 7. Diagrams of changes in water contact angle before and after modification of (a) P-TETA-AO, (b) P-TEPA-AO, and (c) P-PEHA-AO

Download full size | View in the Article

Fig. 8. Effects of pH on uranium removal ratio of (a) P-TETA-AO, (b) P-TEPA-AO and (c) P-PEHA-AO

Download full size | View in the Article

Fig. 9. Dependence of uranium removal ratio on time, pseudo-first-order and pseudo-second-order models kinetic fitting for (a~c) P-TETA-AO, (d~f) P-TEPA-AO, (g~i) P-PEHA-AO

Download full size | View in the Article

Fig. 10. Adsorption properties of (a~b) P-TETA-AO, (c~d) P-TEPA-AO, (e~f) P-PEHA-AO affected by the initial concentration of uranium and adsorption isotherm.

Download full size | View in the Article

Fig. 11. Langmuir and Freundlich isotherms models of (a~b) P-TETA-AO, (c~d) P-TEPA-AO, (e~f) P-PEHA-AO

Download full size | View in the Article

Fig. 12. Uranium removal ratio of P-TETA-AO, P-TEPA-AO, and P-PEHA-AO in simulated seawater.

Download full size | View in the Article

Fig. 13. Adsorption-desorption efficiency of (a) P-TETA-AO, (b)P-TEPA-AO, and (c) P-PEHA-AO for uranium

Download full size | View in the Article

Fig. 14. ATR-FTIR spectra of (a) P-TETA-AO, (b) P-TEPA-AO, and (c) P-PEHA-AO before and after uranium adsorption

Download full size | View in the Article

Fig. 15. (a) XPS spectra of three materials before and after uranium adsorption; (b) U4f spectra after uranium adsorption;(c~k) spectra of various elements before and after uranium adsorption

Download full size | View in the Article

元素Element	U	Zn	V	Cu	Fe	Ni	Co	Pb
浓度 / (μg∙L^-1) Ion concentration	330	400	150	60	100	100	5	3

Table 1. Ions concentration of simulated seawater

View in the Article

准一级动力学模型 Pseudo-first-order adsorption model			准二级动力学模型 Pseudo-second-order adsorption model
	$k_{1}$ / 10^-3(min^-1)	Q_e / (mg·g^-1)	$R_{1}^{2}$	$k_{2}$ / (g·(mg·min)^-1)	Q_e / (mg·g^-1)	$R_{2}^{2}$
P-TETA-AO	12.42	0.244	0.861 0	0.041	1.02	0.998 4
P-TEPA-AO	12.11	0.258	0.882 9	0.029	1.01	0.996 8
P-PEHA-AO	12.19	0.296	0.858 0	0.026	1.01	0.995 0

Table 2. Fitting parameters of pseudo-first-order and pseudo-second-order models for uranium adsorption of P-TETA-AO, P-TEPA-AO, and P-PEHA-AO

View in the Article

Langmuir等温吸附模型 Langmuir isotherm model				Freundlich等温吸附模型 Freundlich isotherm model
	Q_m / (mg·g^-1)	b / (L·mg^-1)	$R_{L}^{2}$	K_F	1/n	$R_{F}^{2}$
P-TETA-AO	66.57	4.248	0.990 7	8.00	0.346	0.607 4
P-TEPA-AO	67.16	2.751	0.993 6	8.12	0.321	0.613 1
P-PEHA-AO	67.52	1.692	0.999 4	8.44	0.308	0.859 8

Table 3. Isotherm adsorption parameters for Langmuir isotherms model and Freundlich isotherm model

View in the Article

Get PDF(in Chinese)

Figures&Tables (18)

References (34)

Copy Citation Text

Wanning REN, Xinxin FENG, Hongwei HAN, Jiangtao HU, Guozhong WU. Preparation of amidoxime-based adsorption materials with a multi-amino synergistic effect and their uranium adsorption performance[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(2): 020202

Download Citation

Save the article for my favorites

Paper Information

Recommended Topics

laser devices and laser physics

Lasers and Laser Optics

laser manufacturing

Instrumentation, Measurement and Metrology

Set citation alerts for the article

Please enter your email address