Fig. 1. Schematic of the light path. The XFEL beam is focused on the sample using the K-B mirror and cleaned by slits. The sample is a pinhole with a diameter of d, L is the distance from the sample to the detector. Three sets of pinhole diffraction data were collected, named experiment 1/2/3, by moving the detector by 10 cm, twice as close to the sample.

Fig. 2. Experimental samples and patterns. (a) The sample is a pinhole. The pinhole effective diameter at the light incident side is 1.025 µm. (b)–(d) Three typical diffraction patterns at positions 1, 2, and 3, respectively. Owing to the beam stop, the central diffraction signal was missing. Patterns 1, 2, and 3 correspond to sample-to-detector distances of L + 20 cm, L + 10 cm, and L, respectively. Patterns display 1000 × 1000 pixels with a pixel size of 15 µm. (e) PSD of pattern 1/2/3. The kth diffraction peak is denoted as ω_k, and the peak spacing between the (k−1)th and kth diffraction peaks is denoted as ω_k−1→k.

Fig. 3. Fitting of average peak periods ω_k−1→k to sample-to-detector distance and single-pulse photon energy statistics. A total of 61 diffraction patterns with high SNR were selected. (a) Linear fitting of ω_k−1→k to sample-to-detector distance. The gray dashed line represents the fitting result, and the slope provides the average wavelength λ = 3.05 ± 0.01 nm, while the intercept gives the sample-to-detector distance L = 16.61 ± 0.03 cm. (b) Single-pulse photon energy statistics. The photon energy for all 61 pulses is shown, where blue, orange, and green correspond to experiments 1/2/3, respectively. The gray dashed line represents the average photon energy of 406.5 eV.

Fig. 4. XAS and spectrometer results. (a) The XAS profile of a 600 nm-thick Si₃N₄ window is represented by the red line, and the reference spectrum is shown in blue from Ref. [38]. X-ray absorption has been converted to normalized optical density. (b) Spectrometer measurement results. The curve represents the normalized pulse photon energy distribution, and the histogram represents the normalized mean photon energy statistics.

Table 1. Spectrometer Results